science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: trifluoroacetyl chloride			Other Names: acetyl chloride, trifluoro-

Formula: CF3CClO					CAS-No.: 354-32-5

Study: photolysis, quantum yield

                
Authors: D.E. Weibel, G.A. Arguello, E.R. de Staricco, E.H. Staricco

Title: Quantum yield in the gas phase photolysis of perfluoroacetyl chloride: a comparison with related compounds

Journal/Source: J. Photochem. Photobiol. A: Chem., 86, 27-31, (1995); doi:10.1016/1010-6030(94)03920-P 


Data: 

Energy/Wavelength range: 254 nm; 280 nm

Resolution: 

Temperature: 

Temperature dependence: 

Pressure/Concentration: 4.6 - 59.9 Torr (with addition of inert gas up to 535.2 Torr)

Phase: gas

pH:


Comments: The quantum yield for the decomposition of CF3COCl taken as PHI(CF3Cl+2C2F6) = 0.98±0.13 was not affected by the total pressure.

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