science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: carbonyl chlorofluoride			Other Names: 

Formula: COClF						CAS-No.: 353-49-1

Study: photolysis, quantum yields

                
Authors: A. Noelle, C. Krumscheid, H. Heydtmann

Title: Determination of quantum yields in the UV photolysis of COF2 and COFCl

Journal/Source: Chem. Phys. Lett., 299, 561-565, (1999); doi:10.1016/S0009-2614(98)01257-3 


Data: table

Energy/Wavelength range: 210 nm, 222.5 nm, 230 nm, 248 nm

Resolution: 

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration: 1.1 - 3.6 mbar

Phase: gas

pH:


Comments: For COFCl the following apparent quantum yields were found: PHI'(210 nm) = 0.90±0.05 (lamp), 
PHI'(210 nm) = 0.85±0.25 (laser), PHI'(222.5 nm) = 0.77±0.33, PHI'(230 nm) = 0.71±0.30 and PHI'(248 nm) = 0.52±0.14.

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