science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: chlorine oxide dimer				Other Names: 

Formula: ClOOCl						CAS-No.: 10049-04-4

Study: UV absorption spectrum, quantum yields, photolysis


Authors: T.A. Moore, M. Okumura, J.W. Seale, T.K. Minton

Title: UV Photolysis of ClOOCl

Journal/Source: J. Phys. Chem. A, 103 (12), 1691-1695, (1999); DOI: 10.1021/jp984410+


Data 

Energy/Wavelength range: 248 nm; 308 nm

Resolution: 

Temperature: 

Temperature dependence: 

Pressure/Concentration:

Phase: gas

pH:


Comments: Photoexcitation of ClOOCl at both 248 and 308 nm leads to dissociation via multiple dynamical pathways, 
producing ClO + ClO and 2Cl + O2. The relative Cl:ClO product yields are 0.88:0.12 and 0.90:0.10 at 248 and 308 nm, respectively.

Author to whom correspondence should be addressed: (e-mail address):