science-softCon uv/vis+ photochemistry database; www.photochemistry.org; (C) science-softCon 2019 Substance: methyl fluoride Other Names: fluoromethane; HFC-41 Formula: CH3F CAS-No.: 593-53-3 Study: photoabsorption, photoionization Authors: T.N. Olney, G. Cooper, W. Fat Chan, G.R. Burton, C.E. Brion, K.H. Tan Title: Quantitative studies of the photoabsorption, photoionization, and ionic photofragmentation of methyl fluoride at VUV and soft X-ray energies (7-250 eV) using dipole electron scattering and synchrotron radiation Journal/Source: Chem. Phys., 189, 733-756, (1994); https://doi.org/10.1016/0301-0104(94)00281-9 Data: table, diagram Energy/Wavelength range: 7 - 250 eV; 8 - 50 eV (~ 5 - 178 nm) Resolution: 1 eV (fwhm); 0.048 eV (fwhm) Temperature: Temperature dependence: Pressure/Concentration: Phase: pH: Comments: Absolute oscillator strengths (cross sections) for the valence shell photoabsorption of CH3F have been measured using low resolution (1 eV fwhm) dipole (e, e) spectroscopy in the equivalent photon energy range from 7 to 250 eV. In addition, high resolution (0.048 eV fwhm) dipole (e, e) spectroscopy has been used to study the valence shell region from 8 to 50 eV in more detail. Author to whom correspondence should be addressed: (e-mail address):