science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2019

Substance: nitryl chloride				Other Names: 

Formula: ClNO2						CAS-No.: 2696-92-6

Study: photochemistry, uv/vis absorption spectrum, kinetics

                
Authors: H.H. Nelson, H.S. Johnston

Title: Kinetics of the Reaction of Cl with ClNO and ClNO2 and the Photochemistry of ClNO2

Journal/Source: J. Phys. Chem., 85, 3891-3896, (1981); DOI: 10.1021/j150625a036


Data: table, diagram

Energy/Wavelength range: 270 - 370 nm

Resolution: 

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration:

Phase: gas

pH:


Comments: The absorption spectrum of ClNO2 was measured in the region 270-370 nm and the photodissociation
channels ClNO2 + hv --> Cl + NO2 and ClNO2 + hv --> ClNO + O were investigated. The quantum yields derived
are Phi(Cl) = 0.93 ± 0.15 and Phi(O) < 0.02.

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