UV/Vis+ Photochemistry Database
Literature-Service: Halogens / Halogen Oxides II
Substances: BrO, BrO-, Br2O, OBrO, BrOCl, F2O, F2O2, FO-, FO2, FC(O)O, IO, IO-, IO3-, OIO, OIO-; I2O
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| Authors | Journal/Source | Title/Paper | Data Sheet |
|---|---|---|---|
| BrO; bromine oxide; CAS-No.: 15656-19-6 | |||
| M. Anbar, I. Dostrovsky | J. Chem. Soc., 1105-1108, (1954) | Ultra-violet absorption spectra of some organic hypohalites |
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| M.A.A. Clyne, H.W. Cruse | Trans. Faraday Soc., 66, 2214-2226, (1970) | Rates of elementary reactions involving the BrO(X2 PI) and IO (X2 PI) radicals. Part 1. - Formation and decay of the BrO radical |
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| N. Basco, S.K. Dogra | Proc. Roy.Soc. London A, 323, 417-429, (1971) | Reactions of halogen oxides studied by flash photolysis. III. The production and reaction of BrO and ClO radicals in the halogen-sensitized decomposition of chlorine dioxide |
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| R.A. Cox, R.A., D.W. Sheppard, M.P. Stevens | Journal of Photochemistry, 19, 189-207, (1982) | Absorption Coefficients and Kinetics of the BrO Radical Using Molecular Modulation |
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| A. Wahner, A.R. Ravishankara, S.P. Sander, R.R. Friedl | Chem. Phys. Lett., 152, 507-512, (1988) | Absorption Cross Section of BrO between 312 and 385 nm at 298 and 223 K |
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| M.K. Gilles, A.A. Turnipseed, J.B. Burkholder, A.R. Ravishankara, S. Solomon | J. Phys. Chem. A., 101(30), 5526-5534, (1997) | Kinetics of the IO Radical. 2. Reaction of IO with BrO |
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| D.M. Wilmouth, T.F. Hanisco, N.M. Donahue, J.G. Anderson | J. Phys.Chem. A, 103, 8935-8945, (1999) | Fourier Transform Ultraviolet Spectroscopy of the A2PI3/2 - X2PI3/2 Transition of BrO |
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| O. Fleischmann, M. Hartmann, J.P. Burrows, J. Orphal | J. Photochem. Photobiol. A: Chem., 168, 117-132, (2004) | New ultraviolet absorption cross-sections of BrO at atmospheric temperatures measured by time-windowing Fourier transform spectroscopy |
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| BrO-; OBr-; hypobromite anion; CAS-No.: 14380-62-2; PubChem: CID 5460626 | |||
| M. Anbar, I. Dostrovsky | J. Chem. Soc., 1105-1108, (1954) | Ultra-violet absorption spectra of some organic hypohalites |
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| H. Galal-Gorchev, J.C. Morris | Inorg. Chem., 4 (6), 899-905, (1965) | Formation and stability of bromamide, bromimide, and nitrogen tribromide in aqueous solution |
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| K. Guo, S. Zheng, X. Zhang, L. Zhao, S. Ji, C. Chen, Z. Wu, D. Wang, J. Fang | Environ. Sci. Technol., 54, 10, 6415–6426, (2020) | Roles of Bromine Radicals and Hydroxyl Radicals in the Degradation of Micropollutants by the UV/Bromine Process |
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| Br2O ; bromine oxide; CAS-No.: 21308-80-5 | |||
| J.J. Orlando, J.B. Burkholder | J. Phys. Chem., 99, 1143-1150, (1994) | Gas Phase UV/Visible Absorption Spectra of HOBr and Br2O |
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| O.V. Rattigan, D.J. Lary, R.L. Jones, R.A. Cox | J. Geophys. Res., 101, 23021-23034, (1996) | UV-visible absorption cross sections of gaseous Br2O and HOBr |
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| B. Deters, J.P. Burrows, S. Himmelmann, C. Blindauer | Annales Geophysicae, 14, 468 - 475, (1997) | Gas phase spectra of HOBr and Br2O and their atmospheric significance |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| H.S.P. Müller, C.E. Miller, E.A. Cohen | Angewandte Chemie International Edition, 35 (18), 2129-2131, (1996) | Dibromine Monoxide, Br2O, and Bromine Dioxide, OBrO: Spectroscopic Properties, Molecular Structures, and Harmonic Force Fields |
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| OBrO; bromine dioxide | |||
| O.V. Rattigan, R.L. Jones, R.A. Cox | Chem. Phys. Lett., 230, 121-126, (1994) | The visible spectrum of gaseous OBrO |
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| C.E. Miller, S.L. Nickolaisen, J.S. Francisco, S.P. Sander | J. Chem. Phys., 107, 2300, (1997) | The OBrO C(2A2) <--- X(2B1) absorption spectrum |
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| J. Kölm, A. Engdahl, O. Schrems, B. Nelander | Chem. Phys., 214, 313-319, (1997) | A spectroscopic and photoisomerisation study of bromine dioxides in argon matrices |
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| G. Knight, A.R. Ravishankara, J.B. Burkholder | J. Phys. Chem. A., 104(47), 11121-11125, (2000) | Laboratory Studies of OBrO |
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| O.C. Fleischmann, J.P. Burrows | priv. comm., (2005) | (298 K) |
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| O.C. Fleischmann, J. Meyer-Arnek, J.P. Burrows, J. Orphal | J. Phys. Chem. A, 109, 5093-5103, (2005) | The Visible Absorption Spectrum of OBrO, Investigated by Fourier Transform Spectroscopy |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| H.S.P. Müller, C.E. Miller, E.A. Cohen | Angewandte Chemie International Edition, 35 (18), 2129-2131, (1996) | Dibromine Monoxide, Br2O, and Bromine Dioxide, OBrO: Spectroscopic Properties, Molecular Structures, and Harmonic Force Fields |
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| BrOCl; bromine chlorine monoxide; CAs-No.: | |||
| J.B. Burkholder, G. Knight, J.J. Orlando | J. Photochem. Photobiol. A: Chem., 134, 133-137, (2000) | UV absorption spectrum of BrOCl |
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| F2O; oxygen difluoride; CAS-No.: 7783-41-7 | |||
| A. Glissmann, H.-J. Schumacher | Z. Physik. Chem. B 24, 328-334 (1934) | Das Spektrum des Fluoroxyds F2O; (273 K) |
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| G. Hettner, R. Pohlman, H.J. Schumacher | Zeitschrift für Physik A, 96, 203-209, (1935) | Das Ultrarotspektrum und die Struktur des F2O |
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| M.M. Maricq, J.J. Szente | J. Phys. Chem., 96, 4925-4930, (1992) | Flash photolysis-time-resolved uv absorption study of the reaction CF3H + F --> CF3 + HF and CF3O2 + CF3O2 --> products |
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| F2O2; dioxygen difluoride; CAS-No.: 7783-44-0 | |||
| P.H.Brodersen, P. Frisch, H.-J. Schumacher | Z. Phys. Chem. B, 37, 25-29, (1937) | Das Absorptionsspektrum des F2O2 |
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| A.D. Kirshenbaum, A.G. Streng | J. Chem. Phys., 35, 1440-1442, (1961) | Molar extinction coefficients of liquid O3F2, O2F2, and O3 in the visible range |
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| P.P. Chegodaev, B.I. Tubikov | Dokl. Akad. Nauk. SSSR, 210, 647-649, (1973) | (193 K) |
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| N.M. Matchuk, V.I. Tupikov, A.I. Malkova, S.Y. Pshezhetskii | Opt. Spektrosk. (Opt. Spectrosc.), 40, 14-18 (17-19), (1976) | (195 K) |
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| J.L. Lyman, R. Holland | J. Phys. Chem., 92, 7232-7241, (1988) | Oxygen Fluoride Chemical Kinetics |
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| FO-; fluorine oxide anion | |||
| M.K. Gilles, M.L. Polak, W.C. Lineberger | J. Chem. Phys., 96, 8012-8020, (1992) | Photoelectron spectroscopy of the halogen oxide anions FO-, ClO-, BrO-, IO-, OClO-, and OIO- |
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| FO2; dioxygen monofluoride; CAS-No.: 15499-23-7 | |||
| J.L. Lyman, R. Holland | J. Phys. Chem., 92, 7232-7241, (1988) | Oxygen Fluoride Chemical Kinetics |
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| T. Ellermann, J. Sehested, O.J. Nielsen, P. Pagsberg, T.J. Wallington | Chem. Phys. Lett., 218, 287-294, (1994) | Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K |
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| Additional datasheets and spectra of FO2 are available at our Spectra Service | |||
| FC(O)O; fluoroformyl radical; CAS-No.: 89831-20-9 | |||
| M.M. Maricq, J.J. Szente, Z. Li, J.S. Francisco | J. Chem. Phys., 98, 784-790, (1993) | Visible absorption spectroscopy of the B2A1-X2B2 transition of fluoroformyl radical, FC(O)O |
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| M.M. Maricq, J.J. Szente, T.S. Dibble, J.S. Francisco | J. Phys. Chem., 98 (47), 12294-12309, (1994) | Atmospheric Chemical Kinetics of FC(O)O |
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| IO ; iodine monoxide; CAS-No.: 14696-98-1 | |||
| E.H. Coleman, A.G. Gaydon, W.M. Vaidya | Nature, 162, 108-109, (1948) | Spectrum of Iodine Oxide (IO) in Flames |
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| R.A. Cox, G.B. Coker | J. Phys. Chem., 87(22), 4478-4484, (1983) | Absorption cross section and kinetics of iodine monoxide (IO) in the photolysis of methyl iodide in the presence of ozone |
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| M.E. Jenkin, R.A. Cox | J. Phys. Chem., 89, 192-199, (1985) | Kinetics study of the reactions IO + NO2 + M --> IONO2 + M, IO + IO --> products, and I + O3 --> IO + O2 |
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| S.P. Sander | J. Phys. Chem., 90(10), 2194-2199, (1986) | Kinetics and mechanism of the IO + IO reaction |
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| R.E. Stickel, A.J. Hynes, J.D. Bradshaw, W.L. Chameides, D.D. Davies | J. Phys. Chem., 92, 1862-1864, (1988) | Absorption cross sections and kinetic considerations of the IO radical as determined by laser flash photolysis/laser absorption spectroscopy |
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| B. Laszlo, M.J. Kurylo, R.E. Huie | J. Phys. Chem., 99, 11701-11707, (1995) | Absorption Cross Sections, Kinetics of Formation, and Self-Reaction of the IO Radical Produced via the Laser Flash Photolysis of N2O/I2/N2 Mixtures |
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| M.H. Harwood, J.B. Burkholder, M. Hunter, R.W. Fox, A.R. Ravishankara | J. Phys. Chem., A, 101, 853-863, (1997) | Absorption Cross Sections and Self-Kinetics of the IO Radical |
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| W.J. Bloss, D.M. Rowley, R.A. Cox, R.L. Jones | J. Phys. Chem. A, 105, 7840-7854, (2001) | Kinetics and Products of the IO Self-Reaction |
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| D. Hölscher | PhD-Thesis, University of Essen, Germany, (2001) | Spektroskopische und kinetische Untersuchungen von IO-Radikalen in der Gasphase |
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| T.J. Dillon, M.E. Tucceri, D. Hoelscher, J.N. Crowley | J. Photochem. Photobio. A: Chemistry, 176, 3 - 14, (2005) | Absorption cross-section of IO at 427.2 nm and 298 K |
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| J.C. Gomez Martin, P. Spietz, J.P. Burrows | J. Photochem. Photobiol. A: Chemistry, 176, 15-38, (2005) | Spectroscopic studies of the I2/O3 photochemistry Part 1: Determination of the absolute absorption cross sections of iodine oxides of atmospheric relevance |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| T. Ingham, M. Cameron, J.N. Crowley | J. Phys. Chem. A, 104, 8001 -8010, (2000) | Photodissociation of IO (355 nm) and OIO (532 nm): Quantum Yields for O(3P) and I(2PJ) Production |
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| IO-; iodine monoxide anion | |||
| M.K. Gilles, M.L. Polak, W.C. Lineberger | J. Chem. Phys., 96, 8012-8020, (1992) | Photoelectron spectroscopy of the halogen oxide anions FO-, ClO-, BrO-, IO-, OClO-, and OIO- |
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| IO3-; iodate; iodate ion; 15454-31-6; PubChem: CID 84927 | |||
| A.D. Awtrey, R.E. Connick | J. Am. Chem. Soc., 73 (4), 1842-1843, (1951) | The Absorption Spectra of I2, I3-, I-, IO3-, S4O6- and S2O3-. Heat of the Reaction I3- = I2 + I- |
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| S.V. Kireev, S.L. Shnyrev | Laser Physics, 25 (7), 075602, (2015) | Study of molecular iodine, iodate ions, iodide ions, and triiodide ions solutions absorption in the UV and visible light spectral bands |
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| OIO; iodine dioxide; 13494-92-3 | |||
| S. Himmelmann, J. Orphal, H. Bovensmann, A. Richter, A. Ladstätter-Weissenmayer, J.P. Burrows | Chem. Phys. Lett., 251, 330-334, (1996) | First observation of the OIO molecule by time-resolved flash photolysis absorption spectroscopy |
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| D.M. Rowley, W.J. Bloss, R.A. Cox, R.L. Jones | J. Phys. Chem. A, 105 (33), 7855-7864, (2001) | Kinetics and Products of the IO + BrO Reaction |
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| D.M. Joseph, S.H. Ashworth, J.M.C. Plane | J. Photochem. Photobio. A: Chemistry, 176, 68 - 77, (2005) | The absorption cross-section and photochemistry of OIO |
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| M.E. Tucceri, D. Hoelscher, A. Rodriguez, T.J. Dillon, J.N. Crowley | Phys. Chem. Chem. Phys., 8, 834 - 846, (2006) | Absorption cross section and photolysis of OIO |
|
| related data (quantum yield studies; photolysis studies) | |||
| T. Ingham, M. Cameron, J.N. Crowley | J. Phys. Chem. A, 104, 8001 -8010, (2000) | Photodissociation of IO (355 nm) and OIO (532 nm): Quantum Yields for O(3P) and I(2PJ) Production |
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| OIO-; iodine dioxide anion | |||
| M.K. Gilles, M.L. Polak, W.C. Lineberger | J. Chem. Phys., 96, 8012-8020, (1992) | Photoelectron spectroscopy of the halogen oxide anions FO-, ClO-, BrO-, IO-, OClO-, and OIO- |
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| I2O; diiodine monoxide; 39319-71-6 | |||
| S.D. Furrow, G.E. Schmitz | Chem. Phys. Lett., 730, 186-190, (2019) | I2O in solution and volatility |
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