UV/Vis+ Photochemistry Database

Courtesy: Elisabeth Noelle Fund for Scientific Data Exchange (non omnis moriar)

Headerbild

UV/Vis+ Photochemistry Database

Literature Service: Halogenated Alkanes II

Substances: Halogenated Methanes II (CCl4, CCl4+, CH3Cl, CD3Cl, CH2Cl2, CHCl3)

The relevant Spectral Data, graphical representations, links to abstracts and other photochemical data & information are available for registered users, see Subscription

Please note: The substance groups are only a rough classification. To search for a specific substance please use the Search Tool or see the CAS-list.

Substances unsorted, use your browser capabilities to search this site or use our Search Tool to search the database.

Authors Journal/Source Title/Paper Data Sheet
CCl4; carbon tetrachloride; tetrachloromethane; CAS-No.: 56-23-5; PubChem: 5943
J.R. Lacher, L.E. Hummel, E.F. Bohmfalk, J.D. Park J. Am. Chem. Soc., 72 (12), 5486-5489, (1950) The Near Ultraviolet Absorption Spectra of Some Fluorinated Derivatives of Methane and Ethylene

H. Tsubomura, K. Kimura, K. Kaya, J. Tanaka, S. Nagakura Bulletin of the Chemical Society of Japan, 37 (3), 417-423, (1964) Vacuum Ultraviolet Absorption Spectra of Saturated Organic Compounds with Non-bonding Electrons

P. J. Bassett, D. R. Lloyd J. Chem. Soc. A, 641 - 645, (1971) Photoelectron spectra of halides. Part I. Tetrafluorides and tetrachlorides of group IVB

B.R. Russell, L.O. Edwards, J.W. Raymonda J. Am. Chem. Soc., 95 (7), 2129-2133, (1973) Vacuum Ultraviolet Absorption Spectra of the Chloromethanes

F.S. Rowland, M.J. Molina Rev. Geophys. Space Science, 13, 1-35, (1975) Chlorofluoromethanes in the Environment 

D.E. Robbins Int. Conf. Stratosphere and Related Problems, Logan (USA), (1976) UV Photoabsorption Cross Section for Halocarbons

G.C. Causley, B.R. Russell J. Electron Spectr. Rel. Phenomena, 11 (4), 383-397, (1977) The vacuum ultraviolet absorption spectra of the group IVA tetrachlorides

C. Hubrich, F. Stuhl J. Photochem., 12, 93- 107, (1980) The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest 

T. Ibuki, N. Takahashi, A. Hiraya, K. Shobatake J. Chem. Phys., 85, 5717, (1986) CCl2(A~1B1) radical formation in VUV photolysis of CCl4 and CBrCl3;

L.C. Lee, M. Suto Chem. Phys., 114, 423-429, (1987) Fluorescence Yields from Photodissociative Excitation of Chloromethanes by Vacuum Ultraviolet Radiation

P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg J. Atmos. Chem., 7, 107-135, (1988) Ultraviolet Absorption Cross-Sections of Chloro and Chlorofluoro-Methanes at Stratospheric Temperatures (210 K, 230 K, 250 K, 270 K, 295 K)

V. Prahlad, V. Kumar J. Quant. Spectrosc. Radiat. Transfer, 54, 945-955, (1995) Temperature Dependence of Photoabsorption Cross Sections of Carbon Tetrachloride at 186-240 nm (220 K, 240 K, 260 K, 280 K, 300 K)

T. N. Olney, N. M. Cann, G. Cooper, C. E. Brion Chem. Phys., 223, 59-98, (1997) Absolute scale determination for photoabsorption spectra and the calculation of molecular properties using dipole sum-rules

G. H. Ho Chem. Phys., 226, 101-111, (1998) Absolute photoabsorption cross section of CCl4 in the energy range 6–250 eV

N. Rontu Carlon, D. K. Papanastasiou, E. L. Fleming, C. H. Jackman, P. A. Newman, J. B. Burkholder Atmos. Chem. Phys., 10, 6137-6149, (2010) UV absorption cross sections of nitrous oxide (N2O) and carbon tetrachloride (CCl4) between 210 and 350K and the atmospheric implications

related data (quantum yield studies; photolysis studies, etc.)
A. Hanf, A. Laeuter, H.-R. Volpp Chem. Phys. Lett., 368, 445-451, (2003) Absolute Chlorine Atom Quantum Yield Measurements in the UV and VUV Gas-phase Laser Photolysis of CCl4

V. Nemtchinov, P. Varanasi J. Quant. Spectr. Rad. Transfer, 82, 473-481, (2003) Thermal infrared absorption cross-sections of CCl4 needed for atmospheric remote sensing

F. Taketani, K. Takahashi, Y. Matsumi J. Phys. Chem. A, 109 (12), 2855-2860, (2005) Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm

M. Tak, M. Chandra, D. Senapati, P.K. Das J. Chem. Sci., 118 (4), 341–344, (2006) Quantum yield of Cl* (2P1/2) production in the gas phase photolysis of CCl4 in the ultraviolet

CCl4+; carbon tetrachloride cation; CAS-No.: 69050-45-9
L. Andrews, B. J. Kelsall, J. H. Miller, B. W. Keelan J. Chem. Soc., Faraday Trans. 2, 79, 1417 - 1424, (1983) Absorption spectrum of the carbon tetrachloride molecular cation in noble-gas matrices

CH3Cl; methyl chloride; chloromethane; CAS-No.: 74-87-3
H. Tsubomura, K. Kimura, K. Kaya, J. Tanaka, S. Nagakura Bulletin of the Chemical Society of Japan, 37 (3), 417-423, (1964) Vacuum Ultraviolet Absorption Spectra of Saturated Organic Compounds with Non-bonding Electrons

B.R. Russell, L.O. Edwards, J.W. Raymonda J. Am. Chem. Soc., 95, 2129-2133, (1973) Vacuum ultraviolet absorption spectra of the chloromethanes

J. W. Raymonda, L. O. Edwards, B. R. Russell J. Am. Chem. Soc., 96 (6), 1708-1712, (1974) Vacuum ultraviolet absorption spectra of some chloroalkanes

D.E. Robbins Geophys. Res. Lett., 3, 213-216, (1976) Photodissociation of Methyl Chloride and Methyl Bromide in the Atmosphere 

C. Hubrich, C. Zetsch, F. Stuhl Ber. Bunsenges. Phys. Chemie, 81, 437-442, (1977) Absorptionsspektren von halogenierten Methanen im Bereich von 275 bis 160 nm bei Temperaturen von 298 und 208 K 

N. Vanlaethem-Meuree, J. Wisemberg, P.C. Simon Bull. Acad. Roy. Belgique, Cl. Sci., 64, 31, (1978) Influence de la temperature sur les sections efficases d'absorption des chlorofluoromethanes dans l'ultraviolet (255 K, 279 K, 296 K)

C.Y.R. Wu, L.C. Lee, D.L. Judge J. Chem. Phys., 71, 5221-5226, (1979) Photoabsorption cross sections of CH3F, CHF3, CH3Cl, and CF2Cl2 from 175 to 760 Å

L.C. Lee, M. Suto Chem. Phys., 114, 423-429, (1987) Fluorescence Yields from Photodissociative Excitation of Chloromethanes by Vacuum Ultraviolet Radiation

P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg J. Atmos. Chem., 7, 107-135, (1988) Ultraviolet Absorption Cross-Sections of Chloro and Chlorofluoro-Methanes at Stratospheric Temperatures (210 K, 230K, 250 K, 270 K, 295 K)

P.B. Roussel, P.D. Lightfoot, F. Caralp, V. Catoire, R. Lesclaux, W. Forst J. Chem. Soc., Faraday Trans., 87, 2367-2377, (1991) Ultraviolet absorption spectra of the CH2Cl and CHCl2 radicals and the kinetics of their self-recombination reactions from 273 to 686 K

T. N. Olney, G. Cooper, Wing Fat Chan, G. R. Burton, C. E. Brion, K. H. Tan Chem. Phys., 205, 421-439, (1996) Absolute photoabsorption (6–350 eV) and photoionization (11–80 eV) of methyl chloride using dipole electron scattering and synchrotron radiation spectroscopies

R.A. Brownsword, M. Hillenkamp, T. Laurent, R.K. Vatsa, H.-R. Volpp, J. Wolfrum J. Chem. Phys., 106, 1359-1366, (1997) Photodissociation dynamics of the chloromethanes at the Lyman-alpha wavelength (121.6 nm)

S.-I. Chou, D. S. Baer, R. K. Hanson Applied Optics, 36 (15), 3288-3293, (1997) Diode laser absorption measurements of CH3Cl and CH4 near 1.65 µm

R.K. Vatsa, H.-R. Volpp Chem. Phys. Let., 340, 289-295, (2001) Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm)

R. Locht, B. Leyh, A. Hoxha, H.W. Jochims, H. Baumgärtel Chem. Phys., 272, 259-275, (2001) UV photoabsorption spectrum of methyl chloride (CH3Cl) and its perdeuterated isotopomer CD3Cl I. A Rydberg series analysis

S. Eden, P. Limão-Vieira, S.V. Hoffmann, N.J. Mason Chem. Phys., 331, 232-244, (2007) VUV spectroscopy of CH3Cl and CH3I

A. Lucchesini, S. Gozzini J. Quant. Spectr. Rad. Transfer, 168, 170-175, (2016) Diode laser spectroscopy of methyl chloride overtones at 850-860 nm

related data (quantum yield studies; photolysis studies, etc.)
R.A. Brownsword, M. Hillenkamp, T. Laurent, R.K. Vatsa, H.-R. Volpp, J. Wolfrum J. Chem. Phys., 106, 1359-1366, (1997) Photodissociation dynamics of the chloromethanes at the Lyman-alpha wavelength (121.6 nm)

CD3Cl; chloromethane-d3; CAS-No.: 1111-89-3
R. Locht, B. Leyh, A. Hoxha, H.W. Jochims, H. Baumgärtel Chem. Phys., 272, 259-275, (2001) UV photoabsorption spectrum of methyl chloride (CH3Cl) and its perdeuterated isotopomer CD3Cl I. A Rydberg series analysis

CH2Cl2; dichloromethane; methylene chloride; CAS-No.: 75-09-2; PubChem: 6344
H. Tsubomura, K. Kimura, K. Kaya, J. Tanaka, S. Nagakura Bulletin of the Chemical Society of Japan, 37 (3), 417-423, (1964) Vacuum Ultraviolet Absorption Spectra of Saturated Organic Compounds with Non-bonding Electrons

N. Vanlaethem-Meurée, J. Wisemberg, P.C. Simon Aeronomica Acta A, 191, 1-17, (1978) Absorption des chlorométhanes dans l'ultraviolet: mesures des sections efficaces d'absorption en fonction de la température

C. Hubrich, F. Stuhl J. Photochem., 12, 93-107, (1980) The Ultraviolet Absorption of Some Halogenated Methanes and Ethanes of Atmospheric Interest 

L.C. Lee, M. Suto Chem. Phys., 114, 423-429, (1987) Fluorescence Yields from Photodissociative Excitation of Chloromethanes by Vacuum Ultraviolet Radiation

P.C. Simon, D. Gillotay, N. Vanlaethem-Meuree, J. Wisemberg J. Atmos. Chem., 7, 107-135, (1988) Ultraviolet Absorption Cross-Sections of Chloro and Chlorofluoro-Methanes at Stratospheric Temperatures (210 K, 230 K, 250 K, 270 K, 295 K)

P.B. Roussel, P.D. Lightfoot, F. Caralp, V. Catoire, R. Lesclaux, W. Forst J. Chem. Soc., Faraday Trans., 87, 2367-2377, (1991) Ultraviolet absorption spectra of the CH2Cl and CHCl2 radicals and the kinetics of their self-recombination reactions from 273 to 686 K

T. Pradeep, D.A. Shirley J. Electr. Spectr. Rel. Phenomena, 66, 125-138, (1993) High resolution photoelectron spectroscopy of CH2F2, CH2Cl2 and CF2Cl2 using supersonic molecular beams

V.L. Orkin, V.G. Khamaganov, A.G. Guschin, R.E. Huie, M.J. Kurylo J. Phys. Chem., 101, 174-178, (1997) Atmospheric Fate of Chlorobromomethane Rate Constant for the Reaction with OH, UV Spectrum, and Water Solubility

R.A. Brownsword, M. Hillenkamp, T. Laurent, R.K. Vatsa, H.-R. Volpp, J. Wolfrum J. Chem. Phys., 106, 1359-1366, (1997) Photodissociation dynamics of the chloromethanes at the Lyman-alpha wavelength (121.6 nm)

R.K. Vatsa, H.-R. Volpp Chem. Phys. Let., 340, 289-295, (2001) Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm)

related data (quantum yield studies; photolysis studies, etc.)
F. Taketani, K. Takahashi, Y. Matsumi J. Phys. Chem. A, 109 (12), 2855-2860, (2005) Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm

CHCl3; chloroform; trichloromethane; CAS-No.: 67-66-3; PubChem: 6212
H. Tsubomura, K. Kimura, K. Kaya, J. Tanaka, S. Nagakura Bulletin of the Chemical Society of Japan, 37 (3), 417-423, (1964) Vacuum Ultraviolet Absorption Spectra of Saturated Organic Compounds with Non-bonding Electrons

G. Lucazeau, C. Sandorfy J. Mol. Spectroscopy, 35, 214-231, (1970) On the far-ultraviolet spectra of some simple aldehydes

N. Vanlaethem-Meurée, J. Wisemberg, P.C. Simon Aeronomica Acta A 191, 1-17 (1978) Absorption des chlorométhanes dans l'ultraviolet: mesures des sections efficaces d'absorption en fonction de la température

C. Hubrich, F. Stuhl J. Photochem., 12, 93-107, (1980) Ultraviolet absorption of some halogenated methanes and ethanes of atmospheric interest

L.C. Lee, M. Suto Chem. Phys., 114, 423-429, (1987) Fluorescence Yields from Photodissociative Excitation of Chloromethanes by Vacuum Ultraviolet Radiation

P.B. Roussel, P.D. Lightfoot, F. Caralp, V. Catoire, R. Lesclaux, W. Forst J. Chem. Soc., Faraday Trans., 87, 2367-2377, (1991) Ultraviolet absorption spectra of the CH2Cl and CHCl2 radicals and the kinetics of their self-recombination reactions from 273 to 686 K

D.P. Seccombe, R.P. Tuckett, H. Baumgärtel, H.W. Jochims Phys. Chem. Chem. Phys., 1, 773-782 (1999) Vacuum-UV fluorescence spectroscopy of CCl3F, CCl3H and CCl3Br in the range 8-30 eV

R.K. Vatsa, H.-R. Volpp Chem. Phys. Let., 340, 289-295, (2001) Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm)

related data (quantum yield studies; photolysis studies, etc.)
R.A. Brownsword, M. Hillenkamp, T. Laurent, R.K. Vatsa, H.-R. Volpp, J. Wolfrum J. Chem. Phys., 106, 1359-1366, (1997) Photodissociation dynamics of the chloromethanes at the Lyman-alpha wavelength (121.6 nm)

F. Taketani, K. Takahashi, Y. Matsumi J. Phys. Chem. A, 109 (12), 2855-2860, (2005) Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm

C. Romanzina, B. Gansa, S. Douina, S. Boyé-Péronne, D. Gauyacq Chem. Phys., 351, 77-82, (2008) 193 nm photolysis of CHCl3: Probe of the CH product by CRDS