UV/Vis+ Photochemistry Database

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UV/Vis+ Photochemistry Database

Literature Service: Halogenated Methyl Radicals

Substances: CH2Br; CH2Cl; CHCl2; CH2I; CCl3; CF2Br; CF3O

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Authors Journal/Source Title/Paper

Data Sheet

CH2Br; bromo methyl radical; CAS-No.: 16519-97-4
O.J. Nielsen, J. Munk, G. Locke, T.J. Wallington J. Phys. Chem., 95, 8714-8719, (1991) Ultraviolet absorption spectra and kinetics of the self-reaction of CH2Br and CH2BrO2 radicals in the gas phase at 298 K

E. Villenave, R. Lesclaux Chem. Phys. Lett., 236, 376-384, (1995) The UV absorption spectra of CH2Br and CH2BrO2 and the reaction kinetics of CH2BrO2 with itself and with HO2 at 298 K

CH2Cl; chloromethyl radical; CAS-No.: 6806-86-6
P.B. Roussel, P.D. Lightfoot, F. Caralp, V. Catoire, R. Lesclaux, W. Forst J. Chem. Soc. Faraday Trans., 87, 2367-2377, (1991) Ultraviolet absorption spectra of the CH2Cl and CHCl2 radicals and the kinetics of their self-recombination reactions from 273 to 686 K

CHCl2; chloromethyl radical; CAS-No.: 3474-12-2
P.B. Roussel, P.D. Lightfoot, F. Caralp, V. Catoire, R. Lesclaux, W. Forst J. Chem. Soc. Faraday Trans., 87, 2367-2377, (1991) Ultraviolet absorption spectra of the CH2Cl and CHCl2 radicals and the kinetics of their self-recombination reactions from 273 to 686 K

CH2I; iodomethyl radical; CAS-No.: 16519-98-5; PubChem: CID 123359
J. Sehested, T. Ellermann, O. J. Nielsen Int. J. Chem. Kinetics, 26 (2), 259-272, (1994) A spectrokinetic study of CH2I and CH2IO2 radicals

CCl3; trichloromethyl radical; CAS-No.: 3170-80-7
F. Danis, F. Caralp, B. Veyret, H. Loirat, R. Lesclaux Int. J. Chem. Kinetics, 21, 715-727, (1989) The UV absorption spectrum of the CCl3 radical and the kinetics of its mutual combination reaction from 253 to 623 K

CF2Br; bromodifluoromethyl radical; CAS-No.: 28882-09-9
R.K. Vatsa, A. Kumar, P.D. Naik, K.V.S. Rama Rao, J.P. Mittal Bulletin of the Chemical Society of Japan, 68, 2817-2822, (1995) Photodissociation of CF2Br2 at 248 nm: A Time-Resolved Absorption Study

CF3O; trifluoromethoxy radical; CAS-No.: 21811-29-0
G. A. Arguello, H. Willner J. Phys. Chem. A, 105, 3466-3470, (2001) IR and UV Absorption Spectrum of the Trifluoromethoxy Radical, CF3O, Isolated in Rare Gas Matrices