UV/Vis+ Photochemistry Database
Literature Service: Halogenated Alkanes
Substances: Iodoalkanes CHI3, CH2I2, CH3I, CH2DI, CD3I, C2H5I, CH3CHI2, C3H7I, CH2ClI, CHClI2, CF3I, CF2I2, C2F3I, C2F5I, C3F7I, C2F4IBr, CH2BrI, n-C4F9CH2CH2I, C4H9I, C10H15I
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| Authors | Journal/Source | Title/Paper | Data Sheet |
|---|---|---|---|
| CHI3; triiodomethane; iodoform; CAS-No.: 75-47-8 | |||
| K. Kimura, S. Nagakura | Spectrochimica Acta, 17, 166-183, (1961) | n --> sigma* Absorption spectra of saturated organic compounds containing bromine and iodine |
|
| related data (quantum yield studies; photolysis studies, etc.) | |||
| M. Kawasaki, S.J. Lee, R. Bersohn | J. Chem. Phys., 63, 809-814, (1975) | Photodissociation of molecular beams of methylene iodide and iodoform |
|
| CH2I2; diiodomethane; CAS-No.: 75-11-6 | |||
| G. Schmitt, F.J. Comes | J. Photochem., 14 (2), 107-123, (1980) | Photolysis of CH2I2 and 1,1-C2H4I2 at 300 nm |
|
| W.H. Pence, S.L. Baughcum, S.R. Leone | J. Phys. Chem., 85, 3844-3851, (1981) | Laser UV photofragmentation of halogenated molecules. Selective bond dissociation and wavelength-specific quantum yields for excited I(2P1/2) and Br(2P1/2) atoms |
|
| W. Schneider, G. von Helden | priv. comm., (1989) | MPI Mainz, 1989 (294 K) |
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| C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, P.J. Crutzen | J. Geophys. Res., 102, 12819-12829, (1997) | Temperature Dependence of UV Absorption Cross Sections and Atmospheric Implications of Several Alkyl Iodides |
|
| J.C. Mössinger, D.E. Shallcross, R.A. Cox | J. Chem. Soc., Faraday Trans., 94, 10 (1998), 1391-1396 | UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2 and CH2BrI |
|
| C.E. Jones, L.J. Carpenter | Environ. Sci. Technol., 39 (16), 6130-6137, (2005) | Solar Photolysis of CH2I2, CH2ICl, and CH2IBr in Water, Saltwater, and Seawater |
|
| T.J. Johnson, T. Masiello, S.W. Sharpe | Atmos. Chem. Phys., 6, 2581–2591, (2006) | The quantitative infrared and NIR spectrum of CH2I2 vapor: vibrational assignments and potential for atmospheric monitoring |
|
| CH3I; methyl iodide; iodomethane; CAS-No.: 74-88-4; PubChem: CID 6328 | |||
| W.C. Price | J. Chem. Phys., 4, 539, (1936) | The Far Ultraviolet Absorption Spectra and Ionization Potentials of the Alkyl Halides. Part I |
|
| D. Porret, C.F. Goodeve | Trans. Faraday Soc., 33, 690, (1937) | The continuous absorption spectrum of methyl iodide |
|
| R.A. Boschi, D.R. Salahub | Molecular Physics, 24 (2), 289-299, (1972) | The far ultra-violet spectra of some 1-iodoalkanes |
|
| W.H. Pence, S.L. Baughcum, S.R. Leone | J. Phys. Chem., 85, 3844-3851, (1981) | Laser UV photofragmentation of halogenated molecules. Selective bond dissociation and wavelength-specific quantum yields for excited I(2P1/2) and Br(2P1/2) atoms |
|
| M.A. Baig, J.P. Connerade, J. Dagata, S.P. McGlynn | J. Phys. B: At. Mol. Phys., 14, L25-L29, (1981) | Quasi-atomic Rydberg states of a complex molecule: CH3I |
|
| J.A. Dagata, G.L. Findley, S.P. McGlynn, J.P. Connerade, M.A. Baig | Physical Review A, 24 (5), 2485, (1981) | Molecular Rydberg transitions. Multichannel approaches to electronic states: CH3I |
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| G. O'Sullivan | J. Phys. B: At. Mol. Phys., 15, L327, (1982) | The absorption spectrum of CH3I in the extreme VUV |
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| W.S. Felps, K. Rupnik, S.P. McGlynn | J. Phys. Chem., 95, 639-656, (1991) | Electronic spectroscopy of the cyanogen halides |
|
| A. Fahr, A.K. Nayak, M.J. Kurylo | Chem. Phys., 197, 195-203, (1995) | The ultraviolet absorption cross sections of CH3I temperature dependent gas and liquid phase measurements |
|
| G.C.G. Waschewsky, R. Horansky, V. Vaida | J. Phys. Chem., 100 (28), 11559 -11565, (1996) | Effect of Dimers on the Temperature-Dependent Absorption Cross Section of Methyl Iodide |
|
| C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, P.J. Crutzen | J. Geophys. Res., 102, 12819-12829, (1997) | Temperature Dependence of UV Absorption Cross Sections and Atmospheric Implications of Several Alkyl Iodides |
|
| O.V. Rattigan, D.E. Shallcross, R.A. Cox | J. Chem. Soc., Faraday Trans., 93, 16, 2839-2846, (1997) | UV absorption cross-sections and atmospheric photolysis rates of CF3I, CH3I, C2H5I and CH2ICl |
|
| T.N. Olney, G. Cooper, C.E. Brion | Chem. Phys., 232, 211-237, (1998) | Quantitative studies of the photoabsorption (4.5–488 eV) and photoionization (9–59.5 eV) of methyl iodide using dipole electron impact techniques |
|
| S. Eden, P. Limão-Vieira, S.V. Hoffmann, N.J. Mason | Chem. Phys., 331, 232-244, (2007) | VUV spectroscopy of CH3Cl and CH3I |
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| R. Locht, B. Leyh, H.W. Jochims, H. Baumgärtel | Chem. Phys., 365, 109-128, (2009) | Medium and high resolution vacuum uv photoabsorption spectroscopy of methyl iodide (CH3I) and its deuterated isotopomers CD3I and CH2DI. a rydberg series analysis |
|
| R. Locht, D. Dehareng, K. Hottmann, H.W. Jochims, H. Baumgärtel, B. Leyh | J. Phys. B, 43 (10), 105101, (2010) | The photoionization dynamics of methyl iodide (CH3I): a joint photoelectron and mass spectrometric investigation |
|
| related data (quantum yield studies; photolysis studies, etc.) | |||
| J. Heicklen, H.S. Johnston | J. Am. Chem. Soc., 84, ,4041 - 4044, (1962) | Photochemical oxidations: II. Methyl iodide |
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| W.P. Hess, R. Naaman, S.R. Leone | J. Phys. Chem., 91 (24), 6085-6087, (1987) | Nonunity quantum yield of excited iodine atoms in the 193 nm photodissociation of methyl iodide |
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| H. Xu, S.T. Pratt | J. Phys. Chem. A, 119 (28), 7548-7558, (2015) | Photodissociation of Methyl Iodide via Selected Vibrational Levels of the B(2E3/2)6s Rydberg state |
|
| CH2DI; methyliodide-d1; CAS-No.: 992-96-1 | |||
| R. Locht, B. Leyh, H.W. Jochims, H. Baumgärtel | Chem. Phys., 365, 109-128, (2009) | Medium and high resolution vacuum uv photoabsorption spectroscopy of methyl iodide (CH3I) and its deuterated isotopomers CD3I and CH2DI. a rydberg series analysis |
|
| CD3I, methyliodide-d3; CAS-No.: 865-50-9 | |||
| R. Locht, B. Leyh, H.W. Jochims, H. Baumgärtel | Chem. Phys., 365, 109-128, (2009) | Medium and high resolution vacuum uv photoabsorption spectroscopy of methyl iodide (CH3I) and its deuterated isotopomers CD3I and CH2DI. a rydberg series analysis |
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| C2H5I; ethyl iodide; CAS-No.: 75-03-6 | |||
| C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, P.J. Crutzen | J. Geophys. Res., 102, 12819-12829, (1997) | Temperature Dependence of UV Absorption Cross Sections and Atmospheric Implications of Several Alkyl Iodides |
|
| O.V. Rattigan, D.E. Shallcross, R.A. Cox | J. Chem. Soc., Faraday Trans., 93, 16, 2839-2846, (1997) | UV absorption cross-sections and atmospheric photolysis rates of CF3I, CH3I, C2H5I and CH2ICl |
|
| G. Friedrichs, D.F. Davidson, R.K. Hanson | Int. J. Chem. Kinet., 34, 374-386, (2002) | Direct measurements of the reaction H + CH2O --> H2 + HCO behind shock waves by means of vis-uv detection of formaldehyde |
|
| C.J. Young, M.D. Hurley, T.J. Wallington, S.A. Mabury | J. Phys. Chem. A, 112 (51), 13542-13548, (2008) | Atmospheric Chemistry of 4:2 Fluorotelomer Iodide (n-C4F9CH2CH2I): Kinetics and Products of Photolysis and Reaction with OH Radicals and Cl Atoms |
|
| related data (quantum yield studies; photolysis studies, etc.) | |||
| A.B. Alekseev, A.M. Pravilov, S.E. Ryabov, O.D. Shestakov | Sov. J. Quantum Electron., 19, 484-486, (1989) | Spectral dependences of the absolute quantum yields of I(2P1/2) atoms in photolysis of C2H5I and C3H7I by lambda = 240-290 nm radiation |
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| CH3CHI2; 1,1-diiodoethane; CAS-No.: 594-02-5 | |||
| G. Schmitt, F.J. Comes | J. Photochem., 14 (2), 107-123, (1980) | Photolysis of CH2I2 and 1,1-C2H4I2 at 300 nm |
|
| C3H7I; propyl iodide; CAS-No.: 107-08-4 | |||
| R.E. Rebbert, S.G. Lias, P. Ausloos | Int. J. Chem. Kinet., 5, 893-908, (1973) | Photolysis of alkyl iodides at 147.0 nm. The reaction H + CnH2n+1I --> HI + CnH2n+1 |
|
| C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, P.J. Crutzen | J. Geophys. Res., 102 (1997), 12819-12829 | Temperature Dependence of UV Absorption Cross Sections and Atmospheric Implications of Several Alkyl Iodides |
|
| related data (quantum yield studies; photolysis studies, etc.) | |||
| A.B. Alekseev, A.M. Pravilov, S.E. Ryabov, O.D. Shestakov | Sov. J. Quantum Electron., 19, 484-486, (1989) | Spectral dependences of the absolute quantum yields of I(2P1/2) atoms in photolysis of C2H5I and C3H7I by lambda = 240-290 nm radiation |
|
| CH2ClI; CH2ICl; chloroiodomethane; iodochloromethane; CAS-No.: 593-71-5 | |||
| C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, P.J. Crutzen | J. Geophys. Res., 102, 12819-12829, (1997) | Temperature Dependence of UV Absorption Cross Sections and Atmospheric Implications of Several Alkyl Iodides |
|
| O.V. Rattigan, D.E. Shallcross, R.A. Cox | J. Chem. Soc., Faraday Trans., 93, 16, 2839-2846, (1997) | UV absorption cross-sections and atmospheric photolysis rates of CF3I, CH3I, C2H5I and CH2ICl |
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| W.M. Kwok, D.L. Phillips | Mol. Phys. 90, 315-326, (1997) | Gas-phase chloroiodomethane short-time photodissociation dynamics in the A-band absorption and a comparison with the solution phase short-time photodissociation dynamics |
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| C.E. Jones, L.J. Carpenter | Environ. Sci. Technol., 39 (16), 6130-6137, (2005) | Solar Photolysis of CH2I2, CH2ICl, and CH2IBr in Water, Saltwater, and Seawater |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| G. Schmitt, F.J. Comes | J. Photochem. Photobiol. A: Chem., 41, 13-30, (1987) | Competitive photodecomposition reactions of chloroiodomethane |
|
| CHClI2; chlorodiiodomethane; diiodochloromethane; CAS-No.: 638-73-3; PubChem: CID 69493 | |||
| K.M. Kapnas, B.W. Toulson, E.S. Foreman, S.A. Block, J.G. Hill, C. Murray | Phys. Chem. Chem. Phys., 19, 31039-31053, (2017) | UV photodissociation dynamics of CHI2Cl and its role as a photolytic precursor for a chlorinated Criegee intermediate |
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| CF3I; iodotrifluoromethane; trifluoroiodomethane; CAS-No.: 2314-97-8 | |||
| L. Brouwer, J. Troe | Chem. Phys. Lett., 82, 1-4, (1981) | Shock wave study of the UV spectrum of CF3I |
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| V.N. Bagratashvili, S.I. Ionov, G.V. Mishakov, V.A. Semchishen | Chem. Phys. Lett., 115, 144-148, (1985) | Photolysis of highly vibrationally excited CF3I molecules by visible laser light |
|
| M.R. Nyden | In: Gann, R.G., Fire Suppression System Performance of Alternative Agents in aircraft Engine and Dry Bay Laboratory Simulations, Vol. 1, Section 3, NIST SP 890, 77-95, (1995) |
Photodegradation of CF3I |
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| A. Fahr, A.K. Nayak, R.E. Huie | Chem. Phys., 199, 275-284, (1995) | Temperature dependence of the ultraviolet absorption cross section of CF3I |
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| O.V. Rattigan, D.E. Shallcross, R.A. Cox | J. Chem. Soc., Faraday Trans., 93, 16, 2839-2846, (1997) | UV absorption cross-sections and atmospheric photolysis rates of CF3I, CH3I, C2H5I and CH2ICl |
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| P. Limão-Vieira, S. Eden, N.J. Mason | Radiation Phys. Chem., 68, 187-192, (2003) | Absolute photo-absorption cross sections and electronic state spectroscopy of selected fluorinated hydrocarbons relevant to the plasma processing industry |
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| S. Eden, P. Limao-Vieira, S.V. Hoffmann, N.J. Mason | Chem. Phys., 323, 313-333, (2006) | VUV photoabsorption in CF3X (X=Cl, Br, I) fluoro-alkanes |
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| T. Tanaka, M. Hoshino, H. Kato, J.R. Harries, Y. Tamenori, K. Ueda H. Tanaka | J. Electron Spectr. Rel. Phenomena, 164, 24-27, (2008) | Photoabsorption spectra of CF3I and thermally dissociated CF3I near the C 1s, I 3d and F 1s ionisation thresholds |
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| J.B. Burkholder, S.P. Sander, J.P.D. Abbatt, J.R. Barker, R.E. Huie, C.E. Kolb, M.J. Kurylo, V.L. Orkin, D.M. Wilmouth, P.H. Wine | Chem. Kin. Photochem. Data for Use in Atmospheric Studies, 18, 4-376, (2015) | Recommended UV absorption cross sections for CF3I at 298 K |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| T.D. Padrick, A.K. Hays, M.A. Palmer | Chem. Phys. Lett., 70, 63-66, (1980) | Broadening of the CF3I UV absorption spectrum by CO2-laser-induced vibrational excitation |
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| G.N.A. Van Veena, T. Ballera, A.E. De Vries, M. Shapiro | Chem. Phys., 93, 277-291, (1985) | Photofragmentation of CF3I in the A band |
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| K.C. Clemitshaw, J.R. Sodeau | J. Photochem. Photobiol. A: Chemistry, 86, 9-14, (1995) | The quantum-yield of formation of CF2O in the gas-phase photo-oxidation of CF3I at 253.7 nm |
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| M.R. Nyden | In: R.G. Gann, Fire Suppression System Performance of Alternative Agents in Aircraft Engine and Dry Bay Laboratory Simulations, Vol. 1, Section 3, NIST SP 890, 77-95, (1995). | Photodegradation of CF3I |
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| K. Kavita, P.K. Das | J. Chem. Phys., 112, 8426, (2000) | Dynamics of I*(2P1/2) production from fluorinated alkyl iodides at 266, 280, and ~305 nm |
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| G. Hancock, A. Hutchinson, R. Peverall, G. Richmond, G.A. Ritchie, S. Taylor | Phys. Chem. Chem. Phys., 9(18), 2234-2239, (2007) | 266 nm photolysis of CF3I and C2F5I studied by diode laser gain FM spectroscopy |
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| CF2I2; difluorodiiodomethane; CAS-No.: 1184-76-5 | |||
| G. Baum, P. Felder, J.R. Huber | J. Chem. Phys., 98, 1999-2010, (1993) | Photofragmentation of CF2I2. Competition between radical and three-body dissociation |
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| J.B. Burkholder, S.P. Sander, J.P.D. Abbatt, J.R. Barker, R.E. Huie, C.E. Kolb, M.J. Kurylo, V.L. Orkin, D.M. Wilmouth, P.H. Wine | Chem. Kin. Photochem. Data for Use in Atmospheric Studies, 18, 4-376, (2015) | Recommended UV absorption cross sections for CF2I2 at 294 K |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| E.A.J. Wannenmacher, P. Felder, J.R. Huber | J. Chem. Phys., 95, 986-997, (1991) | The simultaneous three-body dissociation of CF2I2 |
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| H.A. Scheld, A. Furlan, J.R. Huber | Chem. Phys. Lett., 326, 366-374, (2000) | Formation of molecular iodine by photodissociation of CF2I2 at 193 nm |
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| P.Z. El-Khoury, A.N. Tarnovsky | Chem. Phys. Lett., 453, 160-166, (2008) | Ultrafast formation of I2 following 350-nm photodissociation of CF2I2 in n-hexane |
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| C2F3I; iodotrifluoroethylene; 1,1,2-trifluoro-2-iodoethene; CAS-No.: 359-37-5; PubChem: 67755 | |||
| J. Schander, B.R. Russell | J. Mol. Spectroscopy, 65 (3), 379-387, (1977) | The perfluoro effect on the molecular Rydberg states of bromo- and iodoethylene |
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| C2F5I; pentafluoroethyliodide; CAS-No.: 354-64-3 | |||
| W.H. Pence, S.L. Baughcum, S.R. Leone | J. Phys. Chem., 85 (25), 3844-3851, (1981) | Laser UV photofragmentation of halogenated molecules: Selective bond dissociation and wavelength specific quantum yields for excited I(2P1/2) and Br(2P1/2) atoms |
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| L. Zhang, W. Fuss, K.L. Kompa | Chem. Phys., 144 (2), 289-297, (1990) | Bond-selective photodissociation of CX (X = Br,I) in XC2H4C2F4X |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| K. Kavita, P.K. Das | J. Chem. Phys., 112, 8426, (2000) | Dynamics of I*(2P1/2) production from fluorinated alkyl iodides at 266, 280, and ~305 nm |
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| C3F7I; perfluoropropyl iodide; n-heptafluoropropyl iodide; CAS-No.: 754-34-7 | |||
| H. Hofmann, S.R. Leone | J. Chem. Phys., 69, 3819-3825, (1978) | Tunable laser photodissociation of HgI2: quantum yield for formation of excited I(52P1/2) atoms |
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| J.B. Koffend, S.R. Leone | Chem. Phys. Lett., 81 (1), 136-141, (1981) | Tunable laser photodissociation: Quantum yield of I*(2P1/2) from CH2I2 |
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| W.H. Pence, S.L. Baughcum, S.R. Leone | J. Phys. Chem., 85 (25), 3844-3851, (1981) | Laser UV photofragmentation of halogenated molecules: Selective bond dissociation and wavelength specific quantum yields for excited I(2P1/2) and Br(2P1/2) atoms |
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| S.P. Sander, R.R. Friedl, A.R. Ravishankara, D.M. Golden, C.E. Kolb, M.J. Kurylo, R.E. Huie, M.J. Molina, G.K. Moortgat, B. Finlayson-Pitts | JPL Publication 02-25, (2003) | Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies |
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| C2F4IBr; 1-Bromo-2-iodotetrafluoroethane; CAS-No.: 421-70-5 | |||
| W.H. Pence, S.L. Baughcum, S.R. Leone | J. Phys. Chem., 85 (25), 3844-3851, (1981) | Laser UV photofragmentation of halogenated molecules: Selective bond dissociation and wavelength specific quantum yields for excited I(2P1/2) and Br(2P1/2) atoms |
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| CH2BrI; bromoiodomethane; iodobromomethane; CAS-No.: 557-68-6; PubChem: CID 68407 | |||
| S.-Q. Man, W.M. Kwok, D.L. Phillips, A.E. Johnson | J. Chem. Phys., 105, 5842-5857, (1996) | Short-time photodissociation dynamics of A-band and B-band bromoiodomethane in solution: An examination of bond selective electronic excitation |
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| J.C. Mössinger, D.E. Shallcross, R.A. Cox | J. Chem. Soc., Faraday Trans., 94, 10, 1391-1396, (1998) | UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2 and CH2BrI |
|
| C.E. Jones, L.J. Carpenter | Environ. Sci. Technol., 39 (16), 6130-6137, (2005) | Solar Photolysis of CH2I2, CH2ICl, and CH2IBr in Water, Saltwater, and Seawater |
|
| M. Marcellini, A. Nasedkin, B. Zietz, J. Petersson, J. Vincent, F. Palazzetti, E. Malmerberg, Q. Kong, M. Wulf, D. van der Spoel, R. Neutze, J. Davidsson | J. Chem. Phys., 148, 134307, (2018) | Transient isomers in the photodissociation of bromoiodomethane |
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| P. Recio, J. Cachon, L. Rubio-Lago, D.V. Chicharro, A. Zanchet, P. Limao-Vieira, N. de Oliveira, P.C. Samartzis | J. Phys. Chem., 126, 45, 8404–8422, (2022) | Imaging the Photodissociation Dynamics and Fragment Alignment of CH2BrI at 193 nm |
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| C6H4IF9; n-C4F9CH2CH2I; 4:2 fluorotelomer iodide; CAS-No.: 2043-55-2 | |||
| C.J. Young, M.D. Hurley, T.J. Wallington, S.A. Mabury | J. Phys. Chem. A, 112 (51), 13542-13548, (2008) | Atmospheric Chemistry of 4:2 Fluorotelomer Iodide (n-C4F9CH2CH2I): Kinetics and Products of Photolysis and Reaction with OH Radicals and Cl Atoms |
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| C4H9I; 1-iodobutane; butyl iodide; CAS-No.: 542-69-8; PubChem: CID 10962 | |||
| L. Lagesson-Andrasko, V. Lagesson, J. Andrasko | Anal. Chem., 70 (5), 819-826, (1998) | The use of gas-phase UV spectra in the 168-330 nm wavelength region for analytical purposes. 1. Qualitative measurements |
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| C10H15I; 1-iodoadamantane; adamantyl iodide; CAS-No.: 768-93-4 | |||
| K. Kavita, P.K. Das | J. Chem. Phys., 117, 2038-2044, (2002) | Photodissociation of C6H5I, C6F5I, and related iodides in the ultraviolet |
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