UV/Vis+ Photochemistry Database

Courtesy: Elisabeth Noelle Fund for Scientific Data Exchange (non omnis moriar)

Headerbild

UV/Vis+ Photochemistry Database

Literature Service: Halogenated Carbonyl Compounds II

Substances: FCO, COF2, COCl2, COClF, COFI, COBr2

The relevant Spectral Data, graphical representations, links to abstracts and other photochemical data & information are available for registered users, see Subscription

Please note: The substance groups are only a rough classification. To search for a specific substance please use the Search Tool or see the CAS-list.

Substances unsorted, use your browser capabilities to search this site or use our Search Tool to search the database.

Authors Journal/Source Title/Paper

Data Sheet

FCO; fluoroformyl radical; CAS-No.: 1871-24-5
D.E. Milligan, M.E. Jacox, A.M. Bass, J.J. Comeford, D.E. Mann J. Chem. Phys., 42, 3187-3195, (1965) Matrix-Isolation Study of the Reaction of F Atoms with CO. Infrared and Ultraviolet Spectra of the Free Radical FCO

M.M. Maricq, J.J. Szente, G.A. Khitrov, J.S. Francisco Chem. Phys. Lett., 199, 71-77, (1992) FCO: UV spectrum, self-reaction kinetics and chain reaction with F2

B.A. Williams, J.W. Fleming J. Chem. Phys., 106, 4376-4382, (1997) Laser-induced fluorescence spectrum of the FCO radical

T.J. Wallington, T. Ellermann, O.J. Nielsen, J. Sehested J. Phys. Chem., 98, 2346-2356, (1994) Atmospheric chemistry of FCOx radicals: UV spectra and self-reaction kinetics of FCO and FC(O)O2 and kinetics of some reactions of FCOx with O2, O3, and NO at 296 K

M.M. Maricq, J.S. Szente, Yi Su, J.S. Francisco J. Chem. Phys., 100, 8673-8680, (1994) Ultraviolet spectroscopy of the B 2A and C 2A states of FCO

W.H. Howie, I.C. Lane, A.J. Orr-Ewing J. Chem. Phys., 113, 7237-7251, (2000) The near ultraviolet spectrum of the FCO radical: Re-assignment of transitions and predissociation of the electronically excited state

Additional FCO spectra and datasheets are available via our Spectra Service
COF2; carbonyl fluoride; CAS-No.: 353-50-4
D. E. Milligan, M. E. Jacox, A. M. Bass, J. J. Comeford, D. E. Mann J. Chem. Phys., 42, 3187-3195, (1965) Matrix-Isolation Study of the Reaction of F Atoms with CO. Infrared and Ultraviolet Spectra of the Free Radical FCO

G. L. Workman, A. B. F. Duncan J. Chem. Phys., 52, 3204-3209, (1970) Electronic Spectrum of Carbonyl Fluoride

C.C. Chou, G. Crescentini, H. Vera-Cruiz, W.S. Smith, F.S. Rowland 173rd American Chemical Society Meeting, New Orleans, LA.,(1977) Stratospheric Photochemistry of CF2O, CClFO, and CCl2

L.T. Molina, M.J. Molina 182rd American Chemical Society Meeting, New York, (1982) Chemistry of Fluorine in the Stratosphere 

A. Noelle, H. Heydtmann, R. Meller, G.K. Moortgat Geophys. Res. Lett., 19, 281-284, (1992) UV Absorption Spectra and Absorption Cross Sections of COF2 at 296 K in the Range 200 - 230 nm 

A. Noelle, H. Heydtmann, R. Meller, G.K. Moortgat priv. comm., (1990) University of Frankfurt and MPI Mainz, 1990 

A. Noelle PhD Thesis University of Frankfurt, (1996) Bestimmung von Quantenausbeuten und Absorptiosquerschnitten von COF2 und COFCl im UV-Bereich

related data (quantum yield studies; photolysis studies, etc.)
A. E. Croce, E. Castellano J. Fluorine Chem., 44, 267-273, (1989) Carbonyl fluoride infrared spectrophotometric determination 

A. Noelle, C. Krumscheid, H. Heydtmann Chem. Phys. Lett., 299, 561-565, (1999) Determination of quantum yields in the UV photolysis of COF2 and COFCl

COCl2; carbonyl chloride; phosgene; CAS-No.: 75-44-5
S.R. La Paglia, A.B.F. Duncan J. Chem. Phys., 34, 125-128, (1961) Vacuum Ultraviolet Absorption Spectrum of Phosgene

H. Okabe, A.H. Laufer, J.J. Ball J. Chem. Phys. 55, 373, (1971) Photodissociation of OCCl2 in the Vacuum Ultraviolet: Production and Electronic Energy of Excited Cl2

D.C. Moule, P.D. Foo J. Chem. Phys., 55, 1262 (1971) Analysis of the 2973-Å Absorption System of Phosgene

D. Chadwick Can. J. Chem., 50, 737-746, (1972) Photoelectron spectra of phosgene and thiophosgene

H. Okabe J. Chem. Phys., 66, 2058-2062, (1977) Photodissociation of thiophosgene

C.C. Chou, G. Crescentini, H. Vera-Cruiz, W.S. Smith, F.S. Rowland 173rd American Chemical Society Meeting, New Orleans, LA.,1977 Stratospheric Photochemistry of CF2O, CClFO, and CCl2

W. Schneider, G. von Helden, Wilson, G.K. Moortgat priv. comm., (1987) MPI Mainz, 1987 (294 K)

S. Glicker, H. Okabe J. Phys. Chem., 91, 437-440, (1987) Photochemistry of diacetylene

R. Meller, D. Boglu, G.K. Moortgat Kinetics and Mechanisms for the reactions of halogenated organic compounds in the troposphere.  STEP-HALOCSIDE/AFEAS Workshop, Dublin, Eire, 110-115, (1991) UV spectra of several halogenated carbonyl compounds and FTIR studies on the degradation of CF3COCl, HCFC-123 and HCFC-134a

D. Gillotay, P.C. Simon, L. Dierickx presented at: Quadrennial Ozone Symposium, Charlottesville VA, USA, (1992) Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence

M. Jäger, H. Heydtmann, C. Zetzsch Chem. Phys. Letters, 263, 817-821, (1996) Vacuum Ultraviolet Spectrum and Quantum Yield of the 193 nm Photolysis of Phosgene

M.R.J. Hachey, F. Grein Chem. Phys., 224, 19-31, (1997) Multireference configuration-interaction studies on the UV and photoelectron spectrum of phosgene, Cl2CO

related data (quantum yield studies; photolysis studies, etc.)
M. H. J. Wijnen J. Am. Chem. Soc., 83, 3014-3017, (1961) Photolysis of Phosgene in the Presence of Ethylene

J. Heicklen J. Am. Chem. Soc., 87 (3), 445-453, (1965) The Photolysis of Phosgene-Ethylene Mixtures

T. Einfeld, A. Chichinin, C. Maul, K.-H. Gericke J. Chem. Phys., 116, 2803-2810, (2002) Photodissociation dynamics of phosgene: New observations by applying a three-dimensional imaging technique

COClF; carbonyl chlorofluoride; CAS-No.: 353-49-1
I. Zanon, G. Giacometti, D. Picciol Spectrochimica Acta, 19 (1), 301-306, (1963) The electronic spectrum of FCICO

C.C. Chou, G. Crescentini, H. Vera-Cruiz, W.S. Smith, F.S. Rowland 173rd American Chemical Society Meeting, New Orleans, LA.,(1977) Stratospheric Photochemistry of CF2O, CClFO, and CCl2

A. Noelle, H. Heydtmann, R. Meller, G.K. Moortgat Geophys. Res. Lett., 20, 707-710, (1993) Temperature Dependent UV Absorption Spectra of Carbonyl Chloro-Fluoride

A. Noelle PhD Thesis University of Frankfurt, (1996) Bestimmung von Quantenausbeuten und Absorptiosquerschnitten von COF2 und COFCl im UV-Bereich

related data (quantum yield studies; photolysis studies, etc.)
M. Hermann, A. Noelle, H. Heydtmann Chem. Phys. Lett., 226, 559-562, (1994) Photolysis and quantum yield of carbonylchlorofluoride at 193 nm

A. Noelle, C. Krumscheid, H. Heydtmann Chem. Phys. Lett., 299, 561-565, (1999) Determination of quantum yields in the UV photolysis of COF2 and COFCl

C. Maul, C. Dietrich, T. Haas, K.-H. Gericke Phys. Chem. Chem. Phys., 1, 1441 - 1446, (1999) Photodissociation dynamics of carbonyl chloride fluoride and its implications for phosgene three body decay

COFI; fluorocarbonyl iodide; CAS-No.:
M. S. Chiappero, G. A. Arguello, P. Garcia, H. Pernice, H. Willner, H. Oberhammer, K. A. Peterson, J. S. Francisco Chem. Eur. J., 10, 917-924, (2004) Molecular Structure, Spectroscopy and Matrix Photochemistry of Fluorocarbonyl Iodide, FC(O)I

COBr2; carbonyl bromide; CAS-No.: 593-95-3
H.G. Libuda, F. Zabel, K.H. Becker CEC-Report, STEP-HALOCSIDE/AFEAS Workshop, Dublin, Kinetics and mechanism for the reactions of halogenated organic compounds in the troposphere, 126-131, (1991) UV spectra of some organic chlorine and bromine compounds of atmospheric interest

H.G. Libuda Ph-D-Thesis, (1992) Uni Wuppertal, Germany