UV/Vis+ Photochemistry Database

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UV/Vis+ Photochemistry Database

Literature Service: Halogenated Alkanes IV

Substance: Halogenated Methanes IV (CH3Br, CD3Br, CH2Br2, CHBr3, CBr4, CH2ClBr, CHBr2Cl, CHF2Cl, CHFCl2, CBrCl3, CH3F, CH2F2, CHF3)

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Authors Journal/Source Title/Paper

Data Sheet

CH3Br; methyl bromide; bromomethane; CAS-No.: 74-83-9; PubChem: 6323
G.C. Causley, B.R. Russell J. Chem. Phys., 62, 848-857, (1975) Vacuum ultraviolet absorption spectra of the bromomethanes

D.E. Robbins Geophys. Res. Lett., 3, 213-216, (1976) Photodissociation of Methyl Chloride and Methyl Bromide in the Atmosphere 

A.P. Uthman, P.J. Demlein, T.D. Allston, M.C. Withiam, M.J. McClements, G.A. Takacs J. Phys. Chem., 82, 2252-2257, (1978) Photoabsorption Spectra of Gaseous Methyl Bromide, Ethylene Dibromide, Nitrosyl Bromide, Thionyl Chloride, and Sulfuryl Chloride 

S.P. Sander, M. Peterson, R.T. Watson, R. Patrick J. Phys. Chem., 86, 1236-1240, (1982) Kinetics studies of the HO2 + HO2 and DO2 + DO2 reactions at 298 K

L.T. Molina, M.J. Molina, F.S. Rowland J. Phys. Chem., 86, 2672-2676, (1982) Ultraviolet Absorption Cross Sections of Several Brominated Methanes and Ethanes of Atmospheric Interest 

D. Gillotay P.C. Simon Annales Geophysicae, 6, 211-215, (1988) Ultraviolet Absorption Cross-Sections of Methyl Bromide at Stratospheric Temperatures

T. N. Olney, G. Cooper, Wing Fat Chan, G. R. Burton, C. E. Brion, K. H. Tan Chem. Phys., 218, 127-149, (1997) Absolute photoabsorption and photoionization studies of methyl bromide using dipole electron impact and synchrotron radiation PES techniques

S.N. Kozlov, V.L. Orkin, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 107, (2003), 1333-1338 OH Reactivity and UV Spectra of Propane, n-Propyl Bromide, and  Isopropyl Bromide (295 K)

R. Locht, B. Leyh, H.W. Jochims, H. Baumgärtel Chem. Phys., 317, 73-86, (2005) The vacuum UV photoabsorption spectrum of methyl bromide (CH3Br) and its perdeuterated isotopomer CD3Br: a Rydberg series analysis

F. Kwabia Tchana, D. Jacquemart, N. Lacome, I. Kleiner, J. Orphal J. Mol. Spectroscopy, 235,132–143, (2006) Absolute line intensities in methyl bromide: The 7-micrometer region

related data (quantum yield studies; photolysis studies, etc.)
R. K. Talukdar, G. L. Vaghjiani, A. R. Ravishankara J. Chem. Phys., 96, 8194-8201, (1992) Photodissociation of bromocarbons at 193, 222, and 248 nm: Quantum yields of Br atom at 298 K

CD3Br; bromomethane-d3; CAS-No.: 1111-88-2
A.A. Gordus, R.B. Bernstein J. Chem. Phys., 22, 790-795, (1954) Isotope effect in continuous ultraviolet absorption spectra: Methyl bromide-d3 and chloroform-d

R. Locht, B. Leyh, H.W. Jochims, H. Baumgärtel Chem. Phys., 317, 73-86, (2005) The vacuum UV photoabsorption spectrum of methyl bromide (CH3Br) and its perdeuterated isotopomer CD3Br: a Rydberg series analysis

CH2Br2; dibromomethane; CAS-No.: 74-95-3
L.T. Molina, M.J. Molina, F.S. Rowland J. Phys. Chem., 86, 2672-2676, (1982) Ultraviolet Absorption Cross Sections of Several Brominated Methanes and Ethanes of Atmospheric Interest 

D. Gillotay, P.C. Simon, L. Dierickx Proceedings of Quadrennial Ozone Symposium Goettingen, Germany, (1988) Temperature Dependence of Ultraviolet Absorption Cross-Sections of Brominated Methanes and Ethanes

J.C. Mössinger, D.E. Shallcross, R.A. Cox J. Chem. Soc., Faraday Trans., 94, 10, 1391-1396, (1998) UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2 and CH2BrI 

CHBr3; bromoform; tribromomethane; CAS-No.: 75-25-2; PubChem: 5558
G.C. Causley, B.R. Russell J. Chem. Phys., 62, 848-857, (1975) Vacuum ultraviolet absorption spectra of the bromomethanes

R.A. Cox, S.A. Penkett University of East Anglia, Norwich, (1987) priv. comm. (298 K)

R. Meller, W. Schneider MPI Mainz, (1988) priv. comm. (294 K)

D. Gillotay, A. Jenouvrier, B. Coquart, M.F. Merienne, P.C. Simon Planet. Space Sci., 37, 1127-1140, (1989) Ultraviolet Absorption Cross-Section of Bromoform in the Temperature Range 295-210 K (210 K, 230 K, 250 K, 270 K, 295 K)

G.K. Moortgat, R. Meller, W. Schneider NATO ASI Series, Vol. 17, (1993) Temperature dependence (256-296 K) of the absorption cross-sections of bromoform in the wavelength range 285-360 nm

R.K. Vatsa, H.-R. Volpp Chem. Phys. Let., 340, 289-295, (2001) Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm)

D. K. Papanastasiou, S. A. McKeen, J. B. Burkholder Atmos. Chem. Phys., 14, 3017-3025, (2014) The very short-lived ozone depleting substance CHBr3 (bromoform): revised UV absorption spectrum, atmospheric lifetime and ozone depletion potential

related data (quantum yield studies; photolysis studies, etc.)
K.D. Bayes, R.R. Friedl, S.P. Sander, D.W. Toohey J. Geophys. Res., 108 (D3), 4095, (2003) Measurements of quantum yields of bromine atoms in the photolysis of bromoform from 266 to 324 nm

CBr4; tetrabromomethane; carbon tetrabromide; CAS-No.: 558-13-4; PubChem: 11205
D.A. Bahnick, W.E. Bennett, W.B. Person J. Phys. Chem., 73 (7), 2309-2316, (1969) A spectroscopic study of some CBr4 complexes

G.C. Causley, B.R. Russell J. Chem. Phys., 62, 848-857, (1975) Vacuum ultraviolet absorption spectra of the bromomethanes

CH2ClBr; bromochloromethane; CAS-No.: 74-97-5
V.L. Orkin, V.G. Khamaganov, A.G. Guschin, R.E. Huie, M.J. Kurylo J. Phys. Chem., 101, 174-178, (1997) Atmospheric Fate of Chlorobromomethane Rate Constant for the Reaction with OH, UV Spectrum, and Water Solubility 

CHBr2Cl; chlorodibromomethane; CAS-No.: 124-48-1
T. Ibuki, A. Hiraya, K. Shobatake J. Chem. Phys., 96, 8793, (1992) Vacuum ultraviolet absorption spectra and photodissociative excitation of CHBr2Cl and CHBrCl2

M. Bilde, T.J. Wallington, C. Ferronato, J.J. Orlando, G.S. Tyndall, E. Estupinan, S. Haberkorn J. Phys. Chem. A, 102 (11), 1976-1986, (1998) Atmospheric Chemistry of CH2BrCl, CHBrCl2, CHBr2Cl, CF3CHBrCl, and CBr2Cl2

related data (quantum yield studies; photolysis studies, etc.)
F. Taketani, K. Takahashi, Y. Matsumi J. Phys. Chem. A, 109 (12), 2855-2860, (2005) Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm

CHF2Cl; difluorochloromethane; chlorodifluoromethane; HCFC-22; CAS-No.: 75-45-6; PubChem: 6372
J. Doucet, P. Sauvageau, C. Sandorfy J. Chem. Phys., 58, 3708, (1973) Vacuum ultraviolet and photoelectron spectra of fluoro-chloro derivatives of methane

R.G. Green, R.P. Wayne J. Photochem., 6, 375-377, (1976/77) Vacuum ultraviolet absorption spectra of halogenated methanes and ethanes

R.K. Vatsa, H.-R. Volpp Chem. Phys. Let., 340, 289-295, (2001) Absorption cross-sections for some atmospherically important molecules at the H atom Lyman-alpha wavelength (121.567 nm)

P. Limao-Vieira, E. Vasekova, B. N. Raja Sekhar, N. J. Mason, S. V. Hoffmann Phys. Chem. Chem. Phys., 8, 4766 - 4772, (2006) VUV electronic state spectroscopy of 1,1-difluoroethene and difluorochloromethane by high resolution synchrotron radiation

related data (quantum yield studies; photolysis studies, etc.)
R. A. Brownsword, M. Hillenkamp, T. Laurent, R. K. Vatsa, H.-R. Volpp, J. Wolfrum J. Phys. Chem. A, 101 (6), 995-999, (1997) Photodissociation Dynamics of CHF2Cl after Photoexcitation at the Lyman-alpha Wavelength (121.6 nm)

CHFCl2; fluorodichloromethane; F-21; CAS-No.: 75-43-4
D.E. Robbins, R.S. Stolarski Geophys. Res. Lett., 3, 603-606, (1976) Comparison of stratospheric ozone destruction by fluorocarbons 11, 12, 21, and 22

R.G. Green, R.P. Wayne J. Photochem., 6, 375-377, (1976/77) Vacuum ultraviolet absorption spectra of halogenated methanes and ethanes

C. Hubrich, C. Zetzsch, F. Stuhl Ber. Bunsenges. Phys. Chem., 81, 437-442, (1977) Absorptionsspektren von halogenierten Methanen im Bereich von 275 bis 160 nm bei Temperaturen von 298 und 208 K

B.E. Cole, R.N. Dexter J. Quant. Spectrosc. Radiat. Transfer, 19, 303-309, (1978) Photoabsorption cross sections for chlorinated methanes and ethanes between 46 and 100 Å

P.C. Simon, D. Gillotay, N. Vanlaethem-Meurée, J. Wisemberg J. Atmos. Chem., 7, 107-135, (1988) Ultraviolet absorption cross-sections of chloro- and chlorofluoro-methanes at stratospheric temperatures

related data (quantum yield studies; photolysis studies, etc.)
F. Taketani, K. Takahashi, Y. Matsumi J. Phys. Chem. A, 109 (12), 2855-2860, (2005) Quantum Yields for Cl(2Pj) Atom Formation from the Photolysis of Chlorofluorocarbons and Chlorinated Hydrocarbons at 193.3 nm

CBrCl3; CCl3Br; bromotrichloromethane; trichlorobromomethane; CAS-No.: 75-62-7; PubChem: 6383
P. Cadman, J.P. Simons Trans. Faraday Soc., 62, 631-641, (1966) Reactions of hot halomethyl radicals

H.W. Sidebottom, J.M. Tedder, J.C. Walton Trans. Faraday Soc.,65, 755-762, (1969) Photolysis of bromotrichloromethane

C. Roxlo, A. Mandl J. Appl. Phys., 51, 2969-2972, (1980) Vacuum ultraviolet absorption cross sections for halogen containing molecules

T. Sumiyoshi, K. Tsugaru, M. Katayama Chemistry Letters, 11 (9), 1431-1432, (1982) Picosecond pulse radiolysis of fluorotrichloromethane and bromotrichloromethane

T. Ibuki, N. Takahashi, A. Hiraya, K. Shobatake J. Chem. Phys., 85, 5717-5722, (1986) CCl2(A1B1) radical formation in VUV photolyses of CCl4 and CBrCl3

D.P. Seccombe, R.P. Tuckett, H. Baumgaertel, H.W. Jochims Phys. Chem. Chem. Phys.,1, 773-782, (1999) Vacuum-UV fluorescence spectroscopy of CCl3F, CCl3H and CCl3Br in the range 8-30 eV

related data (quantum yield studies; photolysis studies, etc.)
Y.-J. Jung, M. S. Park, Y. S. Kima, K.-H. Jung, H.-R. Volpp J. Chem. Phys., 111, 4005-4012, (1999) Photodissociation of CBrCl3 at 234 and 265 nm: Evidence of the curve crossing

CH3F; methyl fluoride; HFC-41; CAS-No.: 593-53-3
M. E. Jacox, D. E. Milligan J. Chem. Phys., 50, 3252-3262, (1969) Matrix-Isolation Study of the Vacuum-Ultraviolet Photolysis of Methyl Fluoride. The Infrared Spectra of the Free Radicals CF, HCF, and H2CF

P. Sauvageau, R. Gilbert, P.P. Berlow, C. Sandorfy J. Chem. Phys., 59, 762-765, (1973) Vacuum ultraviolet absorption spectra of fluoromethanes

C.Y.R. Wu, L.C. Lee, D.L. Judge J. Chem. Phys., 71, 5221-5226, (1979) Photoabsorption cross sections of CH3F, CHF3, CH3Cl, and CF2Cl2 from 175 to 760 Å

Terry N. Olney, Glyn Cooper, Wing Fat Chan, Gordon R. Burton, C. E. Brion, K. H. Tan Chem. Phys., 189, 733-756, (1994) Quantitative studies of the photoabsorption, photoionization, and ionic photofragmentation of methyl fluoride at VUV and soft X-ray energies (7-250 eV) using dipole electron scattering and  synchrotron radiation

R. Locht, B. Leyh, A. Hoxha, D. Dehareng, H.W. Jochims, H. Baumgärtel Chem. Phys., 257, 283-299, (2000) About the vacuum UV photoabsorption spectrum of methyl fluoride (CH3F): the fine structure and its vibrational analysis

Yu-Jong Wu, Hui-Fen Chen, Sheng-Lung Chou, Meng-Yeh Lin, Bing-Ming Cheng Chem. Phys. Lett., 497, 12-17, (2010) Vacuum-ultraviolet photolysis of H3CF in solid neon: Infrared spectra of HCF and CF+

A. Lucchesini, S. Gozzini J. Quant. Spectr. Rad. Transfer, 130, 352-358, (2013) Diode laser spectroscopy of methyl fluoride overtones at 850 nm

CH2F2; difluoromethane; methylene fluoride; F 32; CAS-No.: 75-10-5
P. Wagner, A.B.F. Duncan J. Am. Chem. Soc., 77 (9), 2609-2610, (1955) The Vacuum Ultraviolet Absorption Spectrum of Difluoromethane

P. Sauvageau, R. Gilbert, P.P. Berlow, C. Sandorfy J. Chem. Phys., 59, 762-765, (1973) Vacuum ultraviolet absorption spectra of fluoromethanes

T. Pradeep, D.A. Shirley J. Electr. Spectr. Rel. Phenomena, 66, 125-138, (1993) High resolution photoelectron spectroscopy of CH2F2, CH2Cl2 and CF2Cl2 using supersonic molecular beams

D.P. Seccombe, R.Y.L. Chim, R.P. Tuckett, H.W. Jochims, H. Baumgärtel J. Chem. Phys., 114, 4058-4073, (2001) Vacuum-ultraviolet absorption and fluorescence spectroscopy of CF2H2, CF2Cl2, and CF2Br2 in the range 8-22 eV

Aparna Shastri, B. N. Raja Sekhar, Param Jeet Singh, M. N. Deo Spectroscopy Letters, 42 (5), 219-225, (2009) Vacuum Ultraviolet Absorption Spectrum of Difluoromethane Reinvestigated

CHF3; trifluoromethane; fluoroform; CAS-No.: 75-46-7
P. Sauvageau, R. Gilbert, P.P. Berlow, C. Sandorfy J. Chem. Phys., 59, 762-765, (1973) Vacuum ultraviolet absorption spectra of fluoromethanes

C.Y.R. Wu, L.C. Lee, D.L. Judge J. Chem. Phys., 71, 5221-5226, (1979) Photoabsorption cross sections of CH3F, CHF3, CH3Cl, and CF2Cl2 from 175 to 760 Å

M. Suto, L.C. Lee J. Chem. Phys., 79, 1127-1133, (1983) Emission spectra of CF3 radicals. V. Photodissociation of CF3H, CF3Cl, and CF3Br by vacuum ultraviolet

H. Biehl, K.J. Boyle, R.P. Tuckett, H. Baumgärtel, H.W. Jochims Chem. Phys., 214, 367-381, (1997) Vacuum-UV fluorescence spectroscopy of CF3X (X=F, H, Cl, Br) in the range 10-30 eV