UV/Vis+ Photochemistry Database

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UV/Vis+ Photochemistry Database

Literature Service: Nitrogen Oxides

Substances: NO2; NO2-

The relevant Spectral Data, graphical representations, links to abstracts and other photochemical data & information are available for registered users, see Subscription

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Authors Journal/Source Title/Paper

Data Sheet

NO2; nitrogen dioxide; CAS-No.: 10102-44-0
H.H. Holmes, F. Daniels J. Am. Chem. Soc., 56, 630-637, (1934) The Photolysis of Nitrogen Oxides: N2O5, N2O4 and NO2

J.K. Dixon J. Chem. Phys., 8, 157-160, (1940) The Absorption Coefficient of Nitrogen Dioxide in the Visible Spectrum 

T.C. Hall, Jr., F.E. Blacet J. Chem. Phys., 20, 1745-1749, (1952) Separation of the Absorption Spectra of NO2 and N2O4 in the Range of 2400-5000A 

T. Nakayama, M.Y. Kitamura, K. Watanabe J. Chem. Phys., 30, 1180-1186, (1959) Ionization Potential and Absorption Coefficients of Nitrogen Dioxide

A. E. Douglas, K. P. Huber Can. J. Phys., 43(1), 74-81, (1965) The absorption spectrum of NO2 in the 3700 - 4600 Å region

R.D. Hudson Rev. of Geophysics and Space Physics, 9 (2), (1971) Critical review of ultraviolet photoabsorption cross sections for molecules of astrophysical and aeronomic interest

I.T.N. Jones, K.D. Bayes J. Chem. Phys., 59, 4836-4844, (1973) Photolysis of Nitrogen Dioxide

H.S. Johnston, S.-G. Chang, G. Whitten J. Phys. Chem., 78, 1-7, (1974) Photolysis of Nitric Acid Vapor 

H.S. Johnston, R. Graham Can. J. Chem., 52, 1415-1423, (1974) Photochemistry of NOx and HNOx compounds 

A.M. Bass, A.M., A.E. Ledford, Jr., A.H. Lauffer J. Res. NBS, 80A, 143-166, (1976) Extinction Coefficients of NO2 and N2O4  

Y. Morioka, H. Masuko, M. Nakamura, E. Ishiguro, M. Sasanuma J. Phys. B: At. Mol. Phys., 9, 2321, (1976) New Rydberg series of NO2 in the region 500 to 800 AA

A.B. Harker, W. Ho, J.J. Ratto Chem. Phys. Lett., 50, 394 -397, (1977) Photodissociation Quantum Yield of NO2 in the Region 375 to 420 nm 

H. Okabe John Wiley & Sons, New York, (1978) Photochemistry of Small Molecules

E. Hicks, B. Leroy, P. Rigaud, J.-L. Jourdain, G. Le Bras J. Chim. Phys., 76, 693-698, (1979) Spectres d'absorption dans le proche ultraviolet et le visible des composés minoritaires atmosphériques NO2 et SO2 entre 200 et 300 K

T.E. Graedel, C.J. Weschler Reviews of Geophysics, 19 (4), 505-539, (1981) Chemistry within aqueous atmospheric aerosols and raindrops

W. Schneider, G.K. Moortgat, G.S. Tyndall, J.P. Burrows priv. comm., (1986) MPI Mainz, Germany, 1986

W. Schneider, G.K. Moortgat, G.S. Tyndall, J.P. Burrows J. Photochem. Photobiol., 40, 195-217, (1987) Absorption Cross-Sections of NO2 in the UV and Visible Region (200 - 700 nm) at 298 K

J.A. Davidson, C.A. Cantrell, A.H. McDaniel, R.E. Shetter, S. Madronich, J.G. Calvert J. Geophys. Res., 93, 7105-7112, (1988)
Visible-Ultraviolet Absorption Cross Sections for NO2 as a Function of Temperature 

A. P. Zuev, A. Y. Starikovskii J. Applied Spectroscopy, 52, 304-313, (1990) UV absorption cross section of the molecules O2, NO, N2O, CO2, H2O, and NO2

T. C. Corcoran, E. J. Beiting, M. O. Mitchell J. Molecular Spectroscopy, 154, 119-128, (1992) High-resolution absolute absorption cross sections of NO2 at 295, 573, and 673 K at visible wavelengths

A. Amoruso, L. Crescentine, G. Fiocco, M. Volpe J. Geophys. Res., 98, 16857-16863, (1993) New Measurements of the NO2 Absorption Cross Section in the 440- to 460-nm Region and Estimates of the NO2-N2O4 Equilibrium Constant 

M.H. Harwood, R.L. Jones J. Geophys. Res., 99, 22955-22964, (1994) Temperature Dependent Ultraviolet-Visible Absorption Cross Sections of NO2 and N2O4: Low-Temperature Measurements of the Equilibrium Constant of 2NO2<=>N2O4  

B. Coquart, A. Jenouvrier, M. F. Merienne J. Atmos. Chem., 21, 251-261, (1995) The NO2 Absorption Spectrum. II. Absorption Cross-Sections at Low Temperatures in the 400-500 nm Region 

W. Kummer Diploma-Thesis, (1995) University of Essen, Germany, 1995 (298 K)

A.C. Vandaele, C. Hermans, P.C. Simon, M. Van Roozendael, J.M Guilmot, M. Carleer, R. Colin J. Atm. Chem., 25, 289-305, (1996) Fourier Transform Measurement of NO2 Absorption Cross-sections in the Visible Range at Room Temperature 

R. M. Mihalcea, D. S. Baer, R. K. Hanson Applied Optics, 35 (21), 4059-4064, (1996) Tunable diode-laser absorption measurements of NO2 near 670 and 395 nm

J. W. Au, C. E. Brion Chem. Phys., 218, 109-126, (1997) Absolute oscillator strenghts for the valence-shell photoabsorption (2–200 eV) and the molecular and dissociative photoionization (11–80 eV) of nitrogen dioxide

J.W. Harder, J.W. Brault, P.V. Johnston, G.H. Mount J. Geophys. Res., 102, D3, 3861-3879, (1997) Temperature dependent NO2 cross sections at high spectral resolution 

B. Kirmse, A. Delon, R. Jost J. Geophys. Res., 102(D13), 16089-16098, (1997) NO2 absorption cross section and its temperature dependence

J. Orphal, S. Dreher, S. Voigt, J. P. Burrows, R. Jost, A. Delon J. Chem. Phys., 109, 10217-10221, (1998) The near-infrared bands of NO2 observed by high-resolution Fourier-transform spectroscopy

J. P. Burrows, A. Dehn, B. Deters, S. Himmelmann, A. Richter, S. Voigt, J. Orphal J. Quant. Spectr. Rad. Transfer, 60, 1025-1031, (1998) Atmospheric remote-sensing reference data from GOME: Part 1. Temperature-dependent absorption cross-sections of NO2 in the 231-794 nm range

A.C. Vandaele, C. Hermans, P.C. Simon, M. Carleer, R. Colin, S. Fally, M.F. Mérienne, A. Jenouvrier, B. Coquart J. Quant. Spectr. Rad. Transfer, 59, 171-184 (1998) Measurements of the NO2 absorption cross-section from 42000 cm-1 to 10000 cm-1 (238-1000 nm) at 220 K and 294 K

S. Voigt, J. Orphal, J.P. Burrows J. Photochem. Photobiol. A: Chem., 149, 1-7, (2002) The temperature and pressure dependence of the absorption cross-sections of NO2 in the 250-800 nm region measured by Fourier-transform spectroscopy

J. Orphal J. Photochem. Photobiol. A: Chem., 157, 185-209, (2003) A critical review of the absorption cross-sections of O3 and NO2 in the ultraviolet and visible

S. A. Nizkorodov, S. P. Sander, L. R. Brown J. Phys. Chem. A, 108 (22), 4864-4872, (2004) Temperature and Pressure Dependence of High-Resolution Air-Broadened Absorption Cross Sections of NO2 (415-525 nm)

E.A. Volkers, J. Bulthuis, S. Stolte, R. Jost, H. Linnartz J. Molecular Spectroscopy, 237, 259-270, (2006) High resolution electronic study of 16O14N16O, 16O14N18O and 18O14N18O: A  rovibronic survey covering 11 800–14 380 cm−1

B. Gür PhD-Thesis, University of Bremen, Germany, (2006) Temperature Dependent Absorption Cross-Sections of O3 and NO2 in the 240 - 790 nm range determined by using the GOME-2 Satellite Spectrometers for use in Remote Sensing Applications

D. G. Dufour, J. R. Drummond, C. T. McElroy, C. Midwinter, P. F. Bernath, K. A. Walker, C. Nowlan J. Phys. Chem. A, 110 (45), 12414-12418, (2006) Simultaneous Measurements of Visible (400-700 nm) and Infrared (3.4 µm) NO2 Absorption

E.A. Volkers, J. Bulthuis, S. Stolte, R. Jost, N. Wehres, H. Linnartz J. Molecular Spectroscopy, 245, 1-6, (2007) Vibronic spectrum of 15N16O2 between 415 and 440 nm

T. Gherman, D.S. Venables, S. Vaughan, J. Orphal, A.A. Ruth Environ. Sci. Technol., 42 (3), 890-895, (2008) Incoherent Broadband Cavity-Enhanced Absorption Spectroscopy in the near-Ultraviolet: Application to HONO and NO2

H. Fuchs, W.P. Dube, B.M. Lerner, N.L. Wagner, E.J. Williams, S.S. Brown Environ. Sci. Technol., 43 (20), 7831-7836, (2009) A Sensitive and Versatile Detector for Atmospheric NO2 and NOX Based on Blue Diode Laser Cavity Ring-Down Spectroscopy

D. Paul, H. D. Osthoff Anal. Chem., 82(15), 6695-6703, (2010) Absolute measurements of total peroxy nitrate mixing ratios by thermal dissociation blue diode laser cavity ring-down spectroscopy

related data (quantum yield studies; photolysis studies, etc.)
R.G. Dickinson, W.P. Baxter J. Am. Chem. Soc., 1928, 50 (3), 774-782, (1928) The quantum yield in the photochemical decomposition of nitrogen dioxide

J. Troe Zeitschrift für Physikalische Chemie, 214, 573, (2000) Are Primary Quantum Yields of NO2 Photolysis at lambda </= 398 nm Smaller than Unity?

G. Hancock, M. Morrison Molecular Physics, 103 (13), 1727-1733, (2005) The 193 nm photolysis of NO2: NO(v) vibrational distribution, O(1D) quantum yield and emission from vibrationally excited NO2

B. Bohn, F. Rohrer, T. Brauers, A.Wahner Atmos. Chem. Phys., 5, 493–503, (2005) Actinometric measurements of NO2 photolysis frequencies in the atmosphere simulation chamber SAPHIR

Additional datasheets and spectra of NO2 are available at our Spectra Service
NO2-; nitrogen oxide anion; nitrite; CAS-No.: 14797-65-0
S. J. Strickler, M. Kasha J. Am. Chem. Soc., 85 (19), 2899-2901, (1963) Solvent Effects on the Electronic Absorption Spectrum of Nitrite Ion

J. H. Wetters, K. L. Uglum Anal. Chem., 42 (3), 335-340, (1970) Direct spectrophotometric simultaneous determination of nitrite and nitrate in the ultraviolet

A. Treinin, E. Hayon J. Am. Chem. Soc., 92 (20), 5821-5828, (1970) Absorption spectra and reaction kinetics of NO2, N2O3, and N2O4 in aqueous solution

T.E. Graedel, C.J. Weschler Reviews of Geophysics, 19 (4), 505-539, (1981) Chemistry within aqueous atmospheric aerosols and raindrops

K. M. Ervin, J. Ho, W. C. Lineberger J. Phys. Chem., 92(19), 5405-5412, (1988) Ultraviolet photoelectron spectrum of nitrite anion

A. Alif, P. Boule J. Photochem. Photobiol. A: Chem., 59 (3), 357-367, (1991) Photochemistry and environment Part XIV. Phototransformation of nitrophenols induced by excitation of nitrite and nitrate ions

M. Fischer, P. Warneck J. Phys. Chem., 100, 18749-18756, (1996) Photodecomposition of Nitrite and Undissociated Nitrous Acid in Aqueous Solution

Yuegang Zuo, Yiwei Deng Chemosphere, 36, 181-188, (1998) The near-UV absorption constants for nitrite ion in aqueous solution

J. J. Jankowski, D. J. Kieber, K. Mopper Photochemistry and Photobiology, 70(3): 319-328, (1999) Nitrate and Nitrite Ultraviolet Actinometers

E. Riordan, N. Minogue, D. Healy, P. O'Driscoll, J. R. Sodeau J. Phys. Chem. A, 109 (5), 779-786, (2005) Spectroscopic and Optimization Modeling Study of Nitrous Acid in Aqueous Solution

L. Chu, C. Anastasio Environ. Sci. Technol., 41 (10), 3626-3632, (2007) Temperature and Wavelength Dependence of Nitrite Photolysis in Frozen and Aqueous Solutions

related data (quantum yield studies; photolysis studies, etc.)
O. C. Zafiriou, R. Bonneau Photochem. Photobiol., 45, 723-727, (1987) Wavelength-dependent quantum yield of the OH radical formation from photolysis of nitrite ion in water

R. Zellner, M. Exner, H. Herrmann J. Atmos. Chem., 10 (4), 411-425, (1990) Absolute OH quantum yields in the laser photolysis of nitrate, nitrite and dissolved H2O2 at 308 and 351 nm in the temperature range 278-353 K