UV/Vis+ Photochemistry Database

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UV/Vis+ Photochemistry Database

Literature Service: Halogenated Alkenes

Substances: CHBr=CH2, CHCl=CH2, CHCl=CF2, CHF=CH2, CH2=CF2, C2HF3, C3H2F4, CH2=CFCl, cis-CHCl=CHF, trans-CHCl=CHF, CHI=CH2, CHBr=CF2, CFBr=CF2, C2F4, C2F3Cl, C2Cl4, C2H2Cl2, trans-C2H2Cl2, CH2=CBrCF3, CH2=CBrC2F5, CH2=CHC2F4Br, C2HCl3, C3H5Cl, C3H5I, 1,3-C4F6, C4H2Cl4, C4HCl5, C5H2Cl6, cyclo-C5H8, cyclo-C5Cl6, cyclo-C5H2Cl4, trans-CHCl=CHCF3, C2H2Br2, C3H5Br, C4H3BrClF3

The relevant Spectral Data, graphical representations, links to abstracts and other photochemical data & information are available for registered users, see Subscription

Please note: The substance groups are only a rough classification. To search for a specific substance please use the Search Tool or see the Substance-list.

Substances unsorted, use your browser capabilities to search this site or use our Search Tool to search the database.

Authors Journal/Source Title/Paper Data Sheet
C2H3Br; CHBr=CH2; vinyl bromide; bromoethene;  CAS-No.: 593-60-2
D. Chadwick, D.C. Frost, A. Katrib, C.A. McDowell, R.A.N. McLean Can. J. Chem., 50, 2642-2651, (1972) Photoelectron spectra of some bromoethylenes and 2-bromopropene

J. Schander, B.R. Russell J. Am. Chem. Soc., 98, 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

A. Hoxha, R. Locht, B. Leyh, D. Dehareng, K. Hottmann, H.W. Jochims, H. Baumgärtel Chem. Phys., 260, 237-247, (2000) The photoabsorption and constant ionic state spectroscopy of vinylbromide

V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

A. Fahr unpublished data, NIST, (2002) UV spectrum and cross sections of vinyl bromide (C2H3Br)

C2H3Cl; CHCl=CH2; vinyl chloride; chloroethene; CAS-No.: 75-01-4
R. Locht, B. Leyh, K. Hottmann, H. Baumgärtel Chem. Phys., 220, 207-216, (1997) The photoabsorption spectrum of vinylchloride (C2H3Cl) in the 8-12 eV range

P. Limão-Vieira, E. Vasekova, B.N. Raja Sekhar, N.J. Mason, S.V. Hoffmann Chem. Phys., 330, 265-274, (2006) VUV photoabsorption spectroscopy of vinyl chloride studied by high resolution synchrotron radiation

related data (quantum yield studies; photolysis studies, etc.)
Y. Huang, Y.-A. Yang, G.-X. He, R.J. Gordon J. Chem. Phys., 99 (4), 2752-2759, (1993) The ultraviolet photodissociation dynamics of d1-vinyl chloride

C2HClF2; CHCl=CF2; 1-chloro-2,2-difluoroethylene; ethene, 1-chloro-2,2-difluoro-; CAS-No.: 359-10-4
J.D. Scott, B.R. Russell J. Am. Chem. Soc., 94 (8), 2634-2638, (1972) Vacuum-ultraviolet spectral studies of several chlorofluoroethylenes

C2H3F; vinyl fluoride; fluoroethene; CAS-No.: 75-02-5
G. Bélanger, C. Sandorfy J. Chem. Phys., 55, 2055-2060, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

R. Locht, B. Leyh, D. Dehareng, H.W. Jochims, H. Baumgärtel Chem. Phys., 362, 97-108, (2009) The vacuum UV photoabsorption spectroscopy of vinyl fluoride (C2H3F): The vibrational fine structure and its analysis

C2H2F2; CH2=CF2; 1,1-difluoroethylene; CAS-No.: 75-38-7
G. Belanger, C. Sandorfy J. Chem. Phys., 55, 2055-2060, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

D. Reinke, H. Baumgärtel, T. Cvitaš, L. Klasinc, H. Güsten Berichte der Bunsengesellschaft für phys. Chemie, 78 (11), 1145-1147, (1974) Vergleich der Photoelektronenspektren und Photoionenspektren von Vinylfluorid

P. Limao-Vieira, E. Vasekova, B.N. Raja Sekhar, N.J. Mason, S.V. Hoffmann Phys. Chem. Chem. Phys., 8, 4766-4772, (2006) VUV electronic state spectroscopy of 1,1-difluoroethene and difluorochloromethane by high resolution synchrotron radiation

R. Locht, H.W. Jochims, B. Leyh Chem. Phys.,405, 124-136, (2012) The vacuum UV photoabsorption spectroscopy of the geminal ethylene difluoride (1,1-C2H2F2). The vibrational structure and its analysis

related data (quantum yield studies; photolysis studies, etc.)
M. Baasandorj, G. Knight, V. C. Papadimitriou, R. K. Talukdar, A. R. Ravishankara, J. B. Burkholder J. Phys. Chem. A, 114 (13), 4619-4633, (2010) Rate Coefficients for the Gas-Phase Reaction of the Hydroxyl Radical with CH2=CHF and CH2=CF2; Supporting Information from ACS

C2HF3; trifluoroethene; trifluoroethylene; CAS-No.: 359-11-5; PubChem: 9665
G. Belanger, C. Sandorfy J. Chem. Phys., 55, 2055-2060, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

C3H2F4; (1E)-1,3,3,3-tetrafluoro-1-propene; HFO-1234ze; trans-1,3,3,3-tetrafluoro-1-propene; CAS-No.: 29118-24-9; PubChem: CID 5708720
M. Antinolo, I. Bravo, E. Jimenez, B. Ballesteros, J. Albaladejo J. Phys. Chem. A, 121 (43), 8322-8331, (2017) Atmospheric Chemistry of E- and Z-CF3CH=CHF (HFO1234ze): OH Reaction Kinetics as a Function of Temperature and UV  and IR Absorption Cross Sections

C3H2F4; (1Z)-1,3,3,3-tetrafluoro-1-propene; HFO-1234ze; cis-1,3,3,3-tetrafluoro-1-propene; CAS-No.: 29118-25-0
M. Antinolo, I. Bravo, E. Jimenez, B. Ballesteros, J. Albaladejo J. Phys. Chem. A, 121 (43), 8322-8331, (2017) Atmospheric Chemistry of E- and Z-CF3CH=CHF (HFO1234ze): OH Reaction Kinetics as a Function of Temperature and UV  and IR Absorption Cross Sections

C2H2ClF; CH2=CFCl; 1-chloro-1-fluoroethylene; CAS-No.: 2317-91-1
J.D. Scott, B.R. Russell J. Am. Chem. Soc., 94 (8), 2634-2638, (1972) Vacuum-ultraviolet spectral studies of several chlorofluoroethylenes

G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

R. Locht, D. Dehareng, B. Leyh Molecular Physics, 112 (11), 1520-1539, (2014) Vibronic valence and Rydberg transitions in geminal chloro- fluoro-ethene (1,1-C2H2FCl). A spectroscopic and quantum chemical investigation

C2H2ClF; cis-CHCl=CHF; (Z)-1-chloro-2-fluoroethene; CAS-No.: 2268-31-7
G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

C2H2ClF; trans-CHCl=CHF; (E)-1-chloro-2-fluoroethene; CAS-No.: 2268-32-8
G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

C2H3I; CHI=CH2; vinyl iodide; iodoethene; CAS-No.: 593-66-8
S. Yamashita, S. Noguchi, T. Hayakawa Bull. Chem. Soc. Japan, 45 (3), 659-664, (1972) Photodecomposition of Vinyl Iodide in Gas Phase

related data (quantum yield studies; photolysis studies, etc.)
P.C. Roberge, J.A. Herman Can. J. Chem., 45, 1361-1367, (1967) Photolyse de l'iodure de vinyle pur et en solution dans le tétrachlorure de carbone. II. Rendements quantiques

C2HBrF2; CHBr=CF2; 1-bromo-2,2-difluoroethylene; CAS-No.: 359-08-0
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra

C2BrF3; CFBr=CF2; bromotrifluoroethylene; bromotrifluoroethene; CAS-No.: 598-73-2; PubChem: CID 11730
J. Schander, B.R. Russell J. Mol. Spectroscopy, 65 (3), 379-387, (1977) The perfluoro effect on the molecular Rydberg states of bromo- and iodoethylene

V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

C2F4; tetrafluoroethylene; tetrafluoroethene; CAS-No.: 116-14-3
J.R. Dacey, J.G.F. Littler Can. J. Chem., 47, 3871-3875, (1969) Direct photolysis of tetrafluoroethylene at 1849 A

G. Belanger, C. Sandorfy J. Chem. Phys., 55, 2055-2060, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

S. Eden, P. Limão-Vieira, P. A. Kendall, N. J. Mason, J. Delwiche, M.-J. Hubin-Franskin, T. Tanaka, M. Kitajima, H. Tanaka, H. Cho, S. V. Hoffmann Chem. Phys., 297, 257-269, (2004) Electronic excitation of tetrafluoroethylene, C2F4

C2ClF3; Chlorotrifluoroethene; 1-chloro-1,2,2-trifluoroethene; CAS-No.: 79-38-9
J.R. Lacher, L.E. Hummel, E.F. Bohmfalk, J.D. Park J. Am. Chem. Soc., 72 (12), 5486-5489, (1950) The Near Ultraviolet Absorption Spectra of Some Fluorinated Derivatives of Methane and Ethylene

J.D. Scott, B.R. Russell J. Am. Chem. Soc., 94 (8), 2634-2638, (1972) Vacuum-ultraviolet spectral studies of several chlorofluoroethylenes

C2Cl4; tetrachloroethylene; tetrachloroethene; CAS-No.: 127-18-4; PubChem: CID 31373
J.R. Lacher, L.E. Hummel, E.F. Bohmfalk, J.D. Park J. Am. Chem. Soc., 72 (12), 5486-5489, (1950) The Near Ultraviolet Absorption Spectra of Some Fluorinated Derivatives of Methane and Ethylene

C.M. Humphries, A.D. Walsh, P.A. Warsop Trans. Faraday Soc., 63, 513-523, (1967) Ultra-violet absorption spectrum of tetrachloroethylene

M.J. Berry J. Chem. Phys., 61, 3114-3143, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

S. Eden, B. Barc, N.J. Mason, S.V. Hoffmann, Y. Nunes, P. Limão-Vieira Chem. Phys., 365, 150-157, (2009) Electronic state spectroscopy of C2Cl4

C2H2Cl2; 1,1-dichloroethylene; 1,1-dichloroethene; vinylidene chloride; CAS-No.: 75-35-4; PubChem: CID 6366
M.J. Berry J. Chem. Phys., 61, 3114, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

W.R. Haag, M.D. Johnson, R. Scofield Environ. Sci. Technol., 30 (2), 414-421, (1996) Direct photolysis of trichloroethene in air: Effect of cocontaminants, toxicity of products, and hydrothermal treatment of products

R. Locht, D. Dehareng, B. Leyh J. Phys. Comm., 1 (4), 045013, (2017) The vacuum UV photoabsorption spectrum of the Geminal dichloroethylene (1,1-C2H2Cl2) in the 5- 20 eV range. A vibrational  analysis of the valence and Rydberg states

cis-C2H2Cl2; cis-1,2-dichloroethylene; cis-1,2-dichloroethene; CAS-No.: 156-59-2; PubChem: CID 643833
A.D. Walsh, P.A. Warsop Trans. Faraday Soc.,64, 1418-1424, (1968) Ultra-violet absorption spectrum of cis-1,2-dichloro ethylene

M.J. Berry J. Chem. Phys., 61, 3114, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

R. Locht, D. Dehareng, B. Leyh AIP Advances, 9, 015305, (2019) The vacuum UV photoabsorption spectroscopy of the cis-1,2-dichloroethylene (1,2-ClHC=CHCl) in the 5-20 eV range. An experimental and theoretical investigation

trans-C2H2Cl2; trans-1,2-dichloroethylene; trans-1,2-dichloroethene; CAS-No.: 156-60-5; PubChem: CID 638186
A.D. Walsh, P.A. Warsop Trans. Faraday Soc.,64, 1418-1424, (1968) Ultra-violet absorption spectrum of cis-1,2-dichloro ethylene

M.J. Berry J. Chem. Phys., 61, 3114, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

R. Locht, D. Dehareng, B. Leyh J. Quant. Spec. Rad. Transfer, 251, 107048, (2020) The vacuum UV photoabsorption spectroscopy of the trans-dichloroethylene (1,2-ClHC=CClH) in the 5–20 eV range: Experiment and theory

related data (quantum yield studies; photolysis studies, etc.)
K. Seki, T. Kobayashi, K. Ebata J. Photochem. Photobiol. A: Chem., 219, 200-203, (2011) Laser photolysis of trans-dichloroethylene at 193 nm: Quantum yields of photoproducts

C3H2BrF3; CH2=CBrCF3; 2-bromo-3,3,3-trifluoro-1-propene; CAs-No.: 1514-82-5; PubChem: 24879907
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo  J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

C4H2BrF5; CH2=CBrC2F5; 2-bromo-3,3,4,4,4-pentafluoro-1-butene; CAS-No.: 68318-95-6; PubChem: CID 2773404
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

C4H3BrF4; CH2=CHC2F4Br; 4-bromo-3,3,4,4-tetrafluoro-1-butene; CAS-No.: 18599-22-9
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra

C2HCl3; trichloroethylene; trichloroethene; CAS-No.: 79-01-6; PubChem: CID 6575
A.D. Walsh, P.A. Warsop Trans. Faraday Soc.,64, 1425-1431, (1968) Ultra-violet absorption spectrum of trichloro ethylene

M.J. Berry J. Chem. Phys., 61, 3114, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

W.R. Haag, M.D. Johnson, R. Scofield Environ. Sci. Technol., 30 (2), 414-421, (1996) Direct photolysis of trichloroethene in air: Effect of cocontaminants, toxicity of products, and hydrothermal treatment of products

K. Li, M.I. Stefan, J.C. Crittenden Environ. Sci. Technol., 38 (24), 6685-6693, (2004) UV Photolysis of Trichloroethylene: Product Study and Kinetic Modeling

C3H5Cl; allyl chloride; 1-propene, 3-chloro-; CAS-No.: 107-05-1
related data (quantum yield studies; photolysis studies, etc.)
R.W. Phillips, D.H. Volman J. Am. Chem. Soc., 91(13), 3418, (1969) Photolysis of condensed allyl chloride

C3H5I; allyl iodide; 1-propene, 3-iodo-; CAS-No.: 556-56-9
related data (quantum yield studies; photolysis studies, etc.)
W. West, B. Paul Trans. Faraday Soc., 28, 688 - 697, (1932) The quantum yield in the photo-decomposition of the alkyl halides in non-polar solvents

C4F6; hexafluoro-1,3-butadiene; 1,3-butadiene, 1,1,2,3,4,4-hexafluoro-; CAS-No.: 685-63-2
C.R. Brundle, M.B. Robin J. Am. Chem. Soc., 92 (19), 5550-5555, (1970) Nonplanarity in Hexafluorobutadiene as Revealed by Photoelectron and Optical Spectroscopy

F. Ferreira da Silva, D. Almeida, E. Vasekova, E. Drage, N.J. Mason, P. Limão-Vieira Chem. Phys. Lett., 550, 62-66, (2012) High resolution photoabsorption spectrum of hexafluoro-1,3-butadiene (1,3-C4F6) as studied by vacuum ultraviolet (VUV) synchrotron radiation

C4H2Cl4; 1,1,2,3-tetrachlorobutadiene; 1,1,2,3-tetrachlorobuta-1,3-diene; CAS-No.: 921-09-5
M. Lee, T. Merie, D. Rentsch, S. Canonica, U. von Gunten Env. Sci. Tech., 51 (1), 497-505, (2017) Abatement of polychoro-1,3-butadienes in aqueous solution by ozone, UV-photolysis, and advanced oxidation processes (O3/H2O2 and UV/H2O2)

C4H2Cl4; 1,1,4,4-tetrachlorobutadiene; 1,1,4,4-tetrachlorobuta-1,3-diene; CAS-No.: 36038-53-6
M. Lee, T. Merie, D. Rentsch, S. Canonica, U. von Gunten Env. Sci. Tech., 51 (1), 497-505, (2017) Abatement of polychoro-1,3-butadienes in aqueous solution by ozone, UV-photolysis, and advanced oxidation processes (O3/H2O2 and UV/H2O2)

C4HCl5; 1,1,2,4,4-pentachlorobutadiene; pentachlorobutadiene; 1,1,2,4,4-pentachlorobuta-1,3-diene; CAS-No.: 55880-77-8; PubChem: CID 41650
M. Lee, T. Merie, D. Rentsch, S. Canonica, U. von Gunten Env. Sci. Tech., 51 (1), 497-505, (2017) Abatement of polychoro-1,3-butadienes in aqueous solution by ozone, UV-photolysis, and advanced oxidation processes (O3/H2O2 and UV/H2O2)

C5H2Cl6; 1,2,3,3,5,5-hexachlorocyclopentene; CAS-No.: ; PubChem: 19736087
J.D. Idol, C.W. Roberts, E.T. McBee J. Org. Chem., 20 (12), 1743-1749, (1955) The ultraviolet spectra of chlorine-containing cyclopentenes and cyclopentadienes

cyclo-C5Cl8; octachlorocyclopentene; 1,2,3,3,4,4,5,5-octachlorocyclopentene; CAS-No.: 706-78-5
J.D. Idol, C.W. Roberts, E.T. McBee J. Org. Chem., 20 (12), 1743-1749, (1955) The ultraviolet spectra of chlorine-containing cyclopentenes and cyclopentadienes

cyclo-C5Cl6; hexachlorocyclopentadiene; 1,2,3,4,5,5-hexachlorocyclopenta-1,3-diene; CAS-No.: 77-47-4
J.D. Idol, C.W. Roberts, E.T. McBee J. Org. Chem., 20 (12), 1743-1749, (1955) The ultraviolet spectra of chlorine-containing cyclopentenes and cyclopentadienes

cyclo-C5H2Cl4; tetrachlorocyclopentadiene; 1,2,3,4-tetrachlorocyclopenta-1,3-diene; CAS-No.: 695-77-2
J.D. Idol, C.W. Roberts, E.T. McBee J. Org. Chem., 20 (12), 1743-1749, (1955) The ultraviolet spectra of chlorine-containing cyclopentenes and cyclopentadienes

C3H2ClF3; trans-CHCl=CHCF3; trans-1-chloro-3,3,3-trifluoropropene; 3-chloro-1,1,1-trifluoro-2-propene; CAS-No.: 2730-43-0
V.L. Orkin, L.E. Martynova, M.J. Kurylo J. Phys. Chem. A, 118 (28), 5263-5271, (2014) Photochemical Properties of trans-1-Chloro-3,3,3-trifluoropropene (trans-CHCl=CHCF3): OH Reaction Rate Constant, UV and IR Absorption Spectra, Global Warming Potential, and Ozone Depletion Potential

C2H2Br2; 1,1-dibromoethylene; 1,1-dibromoethene; vinylidene bromide; CAS-No.: 593-92-0; PubChem: CID 11652
J. Schander, B.R. Russell J. Am. Chem. Soc., 98 (22), 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

C2H2Br2; cis-1,2-dibromoethylene; cis-1,2-dibromoethene; CAS-No.: 590-11-4; PubChem: CID 643776
J. Schander, B.R. Russell J. Am. Chem. Soc., 98 (22), 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

C2H2Br2; trans-1,2-dibromoethylene; (E)-1,2-dibromoethene; CAS-No.: 540-49-8
J. Schander, B.R. Russell J. Am. Chem. Soc., 98 (22), 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

C3H5Br; allyl bromide; 3-bromoprop-1-ene; 3-bromopropene; CAS-No.: 106-95-6; PubChem: CID 7841
V.D. Nikolic, D.P. Ilic, L.B. Nikolic, M.Z. Stankovic, L.P. Stanojevic, I.M. Savic, I.M. Savic Advanced technologies, 1 (1), 38-46, (2012) The synthesis and structure characterization of deoxyalliin and alliin

C4H3BrClF3; 4-bromo-3-chloro-3,4,4-trifuoro-1-butene; 4-bromo-3-chloro-3,4,4-trifluorobut-1-ene; CAS-No.: 374-25-4
V.L. Orkin, L.E. Martynova, M.J. Kurylo J. Phys. Chem. A, 121 (30), 5675-5680, (2017) Photochemical Properties of CH2=CH-CFCl-CF2Br (4-Bromo-3-chloro-3,4,4-trifuoro-1-butene) and CH3-O-CH(CF3)2  (Methyl Hexafuoroisopropyl Ether): OH Reaction Rate Constants and UV and IR Absorption Spectra