UV/Vis+ Photochemistry Database

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UV/Vis+ Photochemistry Database

Literature Service: Halogenated Alkenes

Substances: CHBr=CH2, CHCl=CH2, CHCl=CF2, CHF=CH2, CH2=CF2, C2HF3, C3H2F4, CH2=CFCl, cis-CHCl=CHF, trans-CHCl=CHF, CHI=CH2, CHBr=CF2, CFBr=CF2, C2F4, C2F3Cl, C2Cl4, C2H2Cl2, trans-C2H2Cl2, CH2=CBrCF3, CH2=CBrC2F5, CH2=CHC2F4Br, C2HCl3, C3H5Cl, C3H5I, 1,3-C4F6, C4H2Cl4, C4HCl5, C5H2Cl6, cyclo-C5H8, cyclo-C5Cl6, cyclo-C5H2Cl4, trans-CHCl=CHCF3, C2H2Br2, C3H5Br, C4H3BrClF3

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Please note: The substance groups are only a rough classification. To search for a specific substance please use the Search Tool or see the CAS-list.

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Authors Journal/Source Title/Paper

Data Sheet

C2H3Br; CHBr=CH2; vinyl bromide; bromoethene;  CAS-No.: 593-60-2
D. Chadwick, D.C. Frost, A. Katrib, C.A. McDowell, R.A.N. McLean Can. J. Chem., 50, 2642-2651, (1972) Photoelectron spectra of some bromoethylenes and 2-bromopropene

J. Schander, B.R. Russell J. Am. Chem. Soc., 98, 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

A. Hoxha, R. Locht, B. Leyh, D. Dehareng, K. Hottmann, H.W. Jochims, H. Baumgärtel Chem. Phys., 260, 237-247, (2000) The photoabsorption and constant ionic state spectroscopy of vinylbromide

V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

A. Fahr unpublished data, NIST, (2002) UV spectrum and cross sections of vinyl bromide (C2H3Br)

C2H3Cl; CHCl=CH2; vinyl chloride; chloroethene; CAS-No.: 75-01-4
R. Locht, B. Leyh, K. Hottmann, H. Baumgärtel Chem. Phys., 220, 207-216, (1997) The photoabsorption spectrum of vinylchloride (C2H3Cl) in the 8-12 eV range

P. Limão-Vieira, E. Vasekova, B.N. Raja Sekhar, N.J. Mason, S.V. Hoffmann Chem. Phys., 330, 265-274, (2006) VUV photoabsorption spectroscopy of vinyl chloride studied by high resolution synchrotron radiation

related data (quantum yield studies; photolysis studies, etc.)
Y. Huang, Y.-A. Yang, G.-X. He, R.J. Gordon J. Chem. Phys., 99 (4), 2752-2759, (1993) The ultraviolet photodissociation dynamics of d1-vinyl chloride

C2HClF2; CHCl=CF2; 1-chloro-2,2-difluoroethylene; ethene, 1-chloro-2,2-difluoro-; CAS-No.: 359-10-4
J.D. Scott, B.R. Russell J. Am. Chem. Soc., 94 (8), 2634-2638, (1972) Vacuum-ultraviolet spectral studies of several chlorofluoroethylenes

C2H3F; vinyl fluoride; fluoroethene; CAS-No.: 75-02-5
G. Bélanger, C. Sandorfy J. Chem. Phys., 55, 2055-2060, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

R. Locht, B. Leyh, D. Dehareng, H.W. Jochims, H. Baumgärtel Chem. Phys., 362, 97-108, (2009) The vacuum UV photoabsorption spectroscopy of vinyl fluoride (C2H3F): The vibrational fine structure and its analysis

C2H2F2; CH2=CF2; 1,1-difluoroethylene; CAS-No.: 75-38-7
G. Belanger, C. Sandorfy J. Chem. Phys., 55, 2055-2060, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

D. Reinke, H. Baumgärtel, T. Cvitaš, L. Klasinc, H. Güsten Berichte der Bunsengesellschaft für phys. Chemie, 78 (11), 1145-1147, (1974) Vergleich der Photoelektronenspektren und Photoionenspektren von Vinylfluorid

P. Limao-Vieira, E. Vasekova, B.N. Raja Sekhar, N.J. Mason, S.V. Hoffmann Phys. Chem. Chem. Phys., 8, 4766-4772, (2006) VUV electronic state spectroscopy of 1,1-difluoroethene and difluorochloromethane by high resolution synchrotron radiation

R. Locht, H.W. Jochims, B. Leyh Chem. Phys.,405, 124-136, (2012) The vacuum UV photoabsorption spectroscopy of the geminal ethylene difluoride (1,1-C2H2F2). The vibrational structure and its analysis

related data (quantum yield studies; photolysis studies, etc.)
M. Baasandorj, G. Knight, V. C. Papadimitriou, R. K. Talukdar, A. R. Ravishankara, J. B. Burkholder J. Phys. Chem. A, 114 (13), 4619-4633, (2010) Rate Coefficients for the Gas-Phase Reaction of the Hydroxyl Radical with CH2=CHF and CH2=CF2; Supporting Information from ACS

C2HF3; trifluoroethene; trifluoroethylene; CAS-No.: 359-11-5; PubChem: 9665
G. Belanger, C. Sandorfy J. Chem. Phys., 55, 2055-2060, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

C3H2F4; (1E)-1,3,3,3-tetrafluoro-1-propene; HFO-1234ze; trans-1,3,3,3-tetrafluoro-1-propene; CAS-No.: 29118-24-9; PubChem: CID 5708720
M. Antinolo, I. Bravo, E. Jimenez, B. Ballesteros, J. Albaladejo J. Phys. Chem. A, 121 (43), 8322-8331, (2017) Atmospheric Chemistry of E- and Z-CF3CH=CHF (HFO1234ze): OH Reaction Kinetics as a Function of Temperature and UV  and IR Absorption Cross Sections

C3H2F4; (1Z)-1,3,3,3-tetrafluoro-1-propene; HFO-1234ze; cis-1,3,3,3-tetrafluoro-1-propene; CAS-No.: 29118-25-0
M. Antinolo, I. Bravo, E. Jimenez, B. Ballesteros, J. Albaladejo J. Phys. Chem. A, 121 (43), 8322-8331, (2017) Atmospheric Chemistry of E- and Z-CF3CH=CHF (HFO1234ze): OH Reaction Kinetics as a Function of Temperature and UV  and IR Absorption Cross Sections

C2H2ClF; CH2=CFCl; 1-chloro-1-fluoroethylene; CAS-No.: 2317-91-1
J.D. Scott, B.R. Russell J. Am. Chem. Soc., 94 (8), 2634-2638, (1972) Vacuum-ultraviolet spectral studies of several chlorofluoroethylenes

G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

R. Locht, D. Dehareng, B. Leyh Molecular Physics, 112 (11), 1520-1539, (2014) Vibronic valence and Rydberg transitions in geminal chloro- fluoro-ethene (1,1-C2H2FCl). A spectroscopic and quantum chemical investigation

C2H2ClF; cis-CHCl=CHF; (Z)-1-chloro-2-fluoroethene; CAS-No.: 2268-31-7
G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

C2H2ClF; trans-CHCl=CHF; (E)-1-chloro-2-fluoroethene; CAS-No.: 2268-32-8
G. Tornow, R. Locht, R. Kaufel, H. Baumgärtel, H.W. Jochims Chem. Phys., 146, 115-128, (1990) The vacuum ultraviolet photoabsorption and photoelectron spectroscopy of fluorochloroethenes. The 1,1-, cis- and trans-C2H2FCl

C2H3I; CHI=CH2; vinyl iodide; iodoethene; CAS-No.: 593-66-8
S. Yamashita, S. Noguchi, T. Hayakawa Bull. Chem. Soc. Japan, 45 (3), 659-664, (1972) Photodecomposition of Vinyl Iodide in Gas Phase

related data (quantum yield studies; photolysis studies, etc.)
P.C. Roberge, J.A. Herman Can. J. Chem., 45, 1361-1367, (1967) Photolyse de l'iodure de vinyle pur et en solution dans le tétrachlorure de carbone. II. Rendements quantiques

C2HBrF2; CHBr=CF2; 1-bromo-2,2-difluoroethylene; CAS-No.: 359-08-0
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra

C2BrF3; CFBr=CF2; bromotrifluoroethylene; bromotrifluoroethene; CAS-No.: 598-73-2; PubChem: CID 11730
J. Schander, B.R. Russell J. Mol. Spectroscopy, 65 (3), 379-387, (1977) The perfluoro effect on the molecular Rydberg states of bromo- and iodoethylene

V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

C2F4; tetrafluoroethylene; tetrafluoroethene; CAS-No.: 116-14-3
J.R. Dacey, J.G.F. Littler Can. J. Chem., 47, 3871-3875, (1969) Direct photolysis of tetrafluoroethylene at 1849 A

G. Belanger, C. Sandorfy J. Chem. Phys., 55, 2055-2060, (1971) Far-Ultraviolet Spectra of Fluoroethylenes

S. Eden, P. Limão-Vieira, P. A. Kendall, N. J. Mason, J. Delwiche, M.-J. Hubin-Franskin, T. Tanaka, M. Kitajima, H. Tanaka, H. Cho, S. V. Hoffmann Chem. Phys., 297, 257-269, (2004) Electronic excitation of tetrafluoroethylene, C2F4

C2ClF3; Chlorotrifluoroethene; 1-chloro-1,2,2-trifluoroethene; CAS-No.: 79-38-9
J.R. Lacher, L.E. Hummel, E.F. Bohmfalk, J.D. Park J. Am. Chem. Soc., 72 (12), 5486-5489, (1950) The Near Ultraviolet Absorption Spectra of Some Fluorinated Derivatives of Methane and Ethylene

J.D. Scott, B.R. Russell J. Am. Chem. Soc., 94 (8), 2634-2638, (1972) Vacuum-ultraviolet spectral studies of several chlorofluoroethylenes

C2Cl4; tetrachloroethylene; tetrachloroethene; CAS-No.: 127-18-4; PubChem: CID 31373
J.R. Lacher, L.E. Hummel, E.F. Bohmfalk, J.D. Park J. Am. Chem. Soc., 72 (12), 5486-5489, (1950) The Near Ultraviolet Absorption Spectra of Some Fluorinated Derivatives of Methane and Ethylene

C.M. Humphries, A.D. Walsh, P.A. Warsop Trans. Faraday Soc., 63, 513-523, (1967) Ultra-violet absorption spectrum of tetrachloroethylene

M.J. Berry J. Chem. Phys., 61, 3114-3143, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

S. Eden, B. Barc, N.J. Mason, S.V. Hoffmann, Y. Nunes, P. Limão-Vieira Chem. Phys., 365, 150-157, (2009) Electronic state spectroscopy of C2Cl4

C2H2Cl2; 1,1-dichloroethylene; 1,1-dichloroethene; vinylidene chloride; CAS-No.: 75-35-4; PubChem: CID 6366
M.J. Berry J. Chem. Phys., 61, 3114, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

W.R. Haag, M.D. Johnson, R. Scofield Environ. Sci. Technol., 30 (2), 414-421, (1996) Direct photolysis of trichloroethene in air: Effect of cocontaminants, toxicity of products, and hydrothermal treatment of products

R. Locht, D. Dehareng, B. Leyh J. Phys. Comm., 1 (4), 045013, (2017) The vacuum UV photoabsorption spectrum of the Geminal dichloroethylene (1,1-C2H2Cl2) in the 5- 20 eV range. A vibrational  analysis of the valence and Rydberg states

cis-C2H2Cl2; cis-1,2-dichloroethylene; cis-1,2-dichloroethene; CAS-No.: 156-59-2; PubChem: CID 643833
A.D. Walsh, P.A. Warsop Trans. Faraday Soc.,64, 1418-1424, (1968) Ultra-violet absorption spectrum of cis-1,2-dichloro ethylene

M.J. Berry J. Chem. Phys., 61, 3114, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

R. Locht, D. Dehareng, B. Leyh AIP Advances, 9, 015305, (2019) The vacuum UV photoabsorption spectroscopy of the cis-1,2-dichloroethylene (1,2-ClHC=CHCl) in the 5-20 eV range. An experimental and theoretical investigation

trans-C2H2Cl2; trans-1,2-dichloroethylene; trans-1,2-dichloroethene; CAS-No.: 156-60-5; PubChem: CID 638186
A.D. Walsh, P.A. Warsop Trans. Faraday Soc.,64, 1418-1424, (1968) Ultra-violet absorption spectrum of cis-1,2-dichloro ethylene

M.J. Berry J. Chem. Phys., 61, 3114, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

related data (quantum yield studies; photolysis studies, etc.)
K. Seki, T. Kobayashi, K. Ebata J. Photochem. Photobiol. A: Chem., 219, 200-203, (2011) Laser photolysis of trans-dichloroethylene at 193 nm: Quantum yields of photoproducts

C3H2BrF3; CH2=CBrCF3; 2-bromo-3,3,3-trifluoro-1-propene; CAs-No.: 1514-82-5; PubChem: 24879907
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo  J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

C4H2BrF5; CH2=CBrC2F5; 2-bromo-3,3,4,4,4-pentafluoro-1-butene; CAS-No.: 68318-95-6; PubChem: CID 2773404
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra 

C4H3BrF4; CH2=CHC2F4Br; 4-bromo-3,3,4,4-tetrafluoro-1-butene; CAS-No.: 18599-22-9
V.L. Orkin, F. Louis, R.E. Huie, M.J. Kurylo J. Phys. Chem., A, 106, 10195-10199, (2002) Photochemistry of Br-containing Fluorinated Alkenes Reactivity towards OH and UV Spectra

C2HCl3; trichloroethylene; trichloroethene; CAS-No.: 79-01-6; PubChem: CID 6575
A.D. Walsh, P.A. Warsop Trans. Faraday Soc.,64, 1425-1431, (1968) Ultra-violet absorption spectrum of trichloro ethylene

M.J. Berry J. Chem. Phys., 61, 3114, (1974) Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products

W.R. Haag, M.D. Johnson, R. Scofield Environ. Sci. Technol., 30 (2), 414-421, (1996) Direct photolysis of trichloroethene in air: Effect of cocontaminants, toxicity of products, and hydrothermal treatment of products

K. Li, M.I. Stefan, J.C. Crittenden Environ. Sci. Technol., 38 (24), 6685-6693, (2004) UV Photolysis of Trichloroethylene: Product Study and Kinetic Modeling

C3H5Cl; allyl chloride; 1-propene, 3-chloro-; CAS-No.: 107-05-1
related data (quantum yield studies; photolysis studies, etc.)
R.W. Phillips, D.H. Volman J. Am. Chem. Soc., 91(13), 3418, (1969) Photolysis of condensed allyl chloride

C3H5I; allyl iodide; 1-propene, 3-iodo-; CAS-No.: 556-56-9
related data (quantum yield studies; photolysis studies, etc.)
W. West, B. Paul Trans. Faraday Soc., 28, 688 - 697, (1932) The quantum yield in the photo-decomposition of the alkyl halides in non-polar solvents

C4F6; hexafluoro-1,3-butadiene; 1,3-butadiene, 1,1,2,3,4,4-hexafluoro-; CAS-No.: 685-63-2
C.R. Brundle, M.B. Robin J. Am. Chem. Soc., 92 (19), 5550-5555, (1970) Nonplanarity in Hexafluorobutadiene as Revealed by Photoelectron and Optical Spectroscopy

F. Ferreira da Silva, D. Almeida, E. Vasekova, E. Drage, N.J. Mason, P. Limão-Vieira Chem. Phys. Lett., 550, 62-66, (2012) High resolution photoabsorption spectrum of hexafluoro-1,3-butadiene (1,3-C4F6) as studied by vacuum ultraviolet (VUV) synchrotron radiation

C4H2Cl4; 1,1,2,3-tetrachlorobutadiene; 1,1,2,3-tetrachlorobuta-1,3-diene; CAS-No.: 921-09-5
M. Lee, T. Merie, D. Rentsch, S. Canonica, U. von Gunten Env. Sci. Tech., 51 (1), 497-505, (2017) Abatement of polychoro-1,3-butadienes in aqueous solution by ozone, UV-photolysis, and advanced oxidation processes (O3/H2O2 and UV/H2O2)

C4H2Cl4; 1,1,4,4-tetrachlorobutadiene; 1,1,4,4-tetrachlorobuta-1,3-diene; CAS-No.: 36038-53-6
M. Lee, T. Merie, D. Rentsch, S. Canonica, U. von Gunten Env. Sci. Tech., 51 (1), 497-505, (2017) Abatement of polychoro-1,3-butadienes in aqueous solution by ozone, UV-photolysis, and advanced oxidation processes (O3/H2O2 and UV/H2O2)

C4HCl5; 1,1,2,4,4-pentachlorobutadiene; pentachlorobutadiene; 1,1,2,4,4-pentachlorobuta-1,3-diene; CAS-No.: 55880-77-8; PubChem: CID 41650
M. Lee, T. Merie, D. Rentsch, S. Canonica, U. von Gunten Env. Sci. Tech., 51 (1), 497-505, (2017) Abatement of polychoro-1,3-butadienes in aqueous solution by ozone, UV-photolysis, and advanced oxidation processes (O3/H2O2 and UV/H2O2)

C5H2Cl6; 1,2,3,3,5,5-hexachlorocyclopentene; CAS-No.: ; PubChem: 19736087
J.D. Idol, C.W. Roberts, E.T. McBee J. Org. Chem., 20 (12), 1743-1749, (1955) The ultraviolet spectra of chlorine-containing cyclopentenes and cyclopentadienes

cyclo-C5Cl8; octachlorocyclopentene; 1,2,3,3,4,4,5,5-octachlorocyclopentene; CAS-No.: 706-78-5
J.D. Idol, C.W. Roberts, E.T. McBee J. Org. Chem., 20 (12), 1743-1749, (1955) The ultraviolet spectra of chlorine-containing cyclopentenes and cyclopentadienes

cyclo-C5Cl6; hexachlorocyclopentadiene; 1,2,3,4,5,5-hexachlorocyclopenta-1,3-diene; CAS-No.: 77-47-4
J.D. Idol, C.W. Roberts, E.T. McBee J. Org. Chem., 20 (12), 1743-1749, (1955) The ultraviolet spectra of chlorine-containing cyclopentenes and cyclopentadienes

cyclo-C5H2Cl4; tetrachlorocyclopentadiene; 1,2,3,4-tetrachlorocyclopenta-1,3-diene; CAS-No.: 695-77-2
J.D. Idol, C.W. Roberts, E.T. McBee J. Org. Chem., 20 (12), 1743-1749, (1955) The ultraviolet spectra of chlorine-containing cyclopentenes and cyclopentadienes

C3H2ClF3; trans-CHCl=CHCF3; trans-1-chloro-3,3,3-trifluoropropene; 3-chloro-1,1,1-trifluoro-2-propene; CAS-No.: 2730-43-0
V.L. Orkin, L.E. Martynova, M.J. Kurylo J. Phys. Chem. A, 118 (28), 5263-5271, (2014) Photochemical Properties of trans-1-Chloro-3,3,3-trifluoropropene (trans-CHCl=CHCF3): OH Reaction Rate Constant, UV and IR Absorption Spectra, Global Warming Potential, and Ozone Depletion Potential

C2H2Br2; 1,1-dibromoethylene; 1,1-dibromoethene; vinylidene bromide; CAS-No.: 593-92-0; PubChem: CID 11652
J. Schander, B.R. Russell J. Am. Chem. Soc., 98 (22), 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

C2H2Br2; cis-1,2-dibromoethylene; cis-1,2-dibromoethene; CAS-No.: 590-11-4; PubChem: CID 643776
J. Schander, B.R. Russell J. Am. Chem. Soc., 98 (22), 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

C2H2Br2; trans-1,2-dibromoethylene; (E)-1,2-dibromoethene; CAS-No.: 540-49-8
J. Schander, B.R. Russell J. Am. Chem. Soc., 98 (22), 6900-6904, (1976) Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes

C3H5Br; allyl bromide; 3-bromoprop-1-ene; 3-bromopropene; CAS-No.: 106-95-6; PubChem: CID 7841
V.D. Nikolic, D.P. Ilic, L.B. Nikolic, M.Z. Stankovic, L.P. Stanojevic, I.M. Savic, I.M. Savic Advanced technologies, 1 (1), 38-46, (2012) The synthesis and structure characterization of deoxyalliin and alliin

C4H3BrClF3; 4-bromo-3-chloro-3,4,4-trifuoro-1-butene; 4-bromo-3-chloro-3,4,4-trifluorobut-1-ene; CAS-No.: 374-25-4
V.L. Orkin, L.E. Martynova, M.J. Kurylo J. Phys. Chem. A, 121 (30), 5675-5680, (2017) Photochemical Properties of CH2=CH-CFCl-CF2Br (4-Bromo-3-chloro-3,4,4-trifuoro-1-butene) and CH3-O-CH(CF3)2  (Methyl Hexafuoroisopropyl Ether): OH Reaction Rate Constants and UV and IR Absorption Spectra